On the thermodynamic theory of the strength of solids: 4. Capillary condensation and capillary evaporation in wedge-shaped crack

• Published in: Colloid journal of the Russian Academy of Sciences Vol. 76; no. 2; pp. 176 - 181
• Main Author: Rusanov, A. I.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.03.2014
• Subjects: Chemistry; Chemistry and Materials Science; Polymer Sciences; Surfaces and Interfaces; Thin Films; Crack Mouth; Thermodynamic Theory; Colloid Journal; Capillary Condensation; Contact Angle
• DOI: 10.1134/S1061933X14010104
• ISSN: 1061-933X

The processes of capillary condensation and capillary evaporation in a wedge-shaped crack are considered. Capillary evaporation is a comparatively new phenomenon that is opposite to capillary condensation and occurs upon the cleavage of a solid in a nonwetting liquid. For both cases, the positions of a meniscus inside a wedge-shaped crack have been calculated as functions of the meniscus curvature radius, liquid-contact angle, and crack-opening angle. The effect of temperature on the meniscus position has been analyzed; it has been established that the meniscus shifts from the gaseous toward the liquid phase as temperature rises. The regularities of meniscus displacements in the course of crack growth have been established: under the conformal mechanism of crack growth, the absolute position of the meniscus remains unchanged (i.e., the meniscus and the crack frontal line move at the same velocity), while, under the depth mechanism of growth, the relative position of the meniscus is retained.