Functions of organoaluminum and proton donor compounds in the formation and functioning of nanosized Ziegler-type nickel-containing hydrogenation catalysts
The turnover frequency (TOF) and turnover number (TON) in styrene hydrogenation have been determined for catalytic systems based on Ni(acac) 2 · n H 2 O ( n = 0, 0.5, and 3.0), Ni(COD) 2 (COD = cycloocta-1,5-diene), and AlEt 3 at different Al/Ni molar ratios. The amount of water of crystallization d...
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| Published in | Kinetics and catalysis Vol. 56; no. 5; pp. 574 - 583 |
|---|---|
| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Moscow
Pleiades Publishing
01.09.2015
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| Abstract | The turnover frequency (TOF) and turnover number (TON) in styrene hydrogenation have been determined for catalytic systems based on Ni(acac)
2
·
n
H
2
O (
n
= 0, 0.5, and 3.0), Ni(COD)
2
(COD = cycloocta-1,5-diene), and AlEt
3
at different Al/Ni molar ratios. The amount of water of crystallization determines the TON and TOF of the nickel catalysts and their dependence on the Al/Ni ratio. The TON and TOF of the nickel catalysts are markedly increased by the introduction of an optimum amount of a proton donor. The model of the ligand shell stabilizing the nickel nanoparticles has been refined. The refined model provides an explanation for the activating action of proton donor compounds in the formation of the hydrogenation catalysts. The functions of the organoaluminum compounds are not limited to Ni(II) reduction to Ni(0); they are also involved in the stabilization of the nickel-containing nanoparticles. |
|---|---|
| AbstractList | The turnover frequency (TOF) and turnover number (TON) in styrene hydrogenation have been determined for catalytic systems based on Ni(acac)
2
·
n
H
2
O (
n
= 0, 0.5, and 3.0), Ni(COD)
2
(COD = cycloocta-1,5-diene), and AlEt
3
at different Al/Ni molar ratios. The amount of water of crystallization determines the TON and TOF of the nickel catalysts and their dependence on the Al/Ni ratio. The TON and TOF of the nickel catalysts are markedly increased by the introduction of an optimum amount of a proton donor. The model of the ligand shell stabilizing the nickel nanoparticles has been refined. The refined model provides an explanation for the activating action of proton donor compounds in the formation of the hydrogenation catalysts. The functions of the organoaluminum compounds are not limited to Ni(II) reduction to Ni(0); they are also involved in the stabilization of the nickel-containing nanoparticles. |
| Author | Shmidt, F. K. Titova, Yu. Yu Belykh, L. B. |
| Author_xml | – sequence: 1 givenname: F. K. surname: Shmidt fullname: Shmidt, F. K. email: fkschmidt@chem.isu.ru organization: Irkutsk State University – sequence: 2 givenname: Yu. Yu surname: Titova fullname: Titova, Yu. Yu organization: Irkutsk State University – sequence: 3 givenname: L. B. surname: Belykh fullname: Belykh, L. B. organization: Irkutsk State University |
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| Cites_doi | 10.1016/0304-5102(81)85078-X 10.1021/cm0111837 10.1016/0022-328X(90)85232-N 10.1021/ja00907a023 10.1134/S0023158412050151 10.1002/anie.197309431 10.1021/ic101237c 10.1246/bcsj.55.325 10.1007/s11173-005-0159-2 10.1134/S1070427210110030 10.1021/jp022615j 10.1016/j.molcata.2005.02.033 10.1016/j.molcata.2009.07.007 10.1134/S0023158406010095 10.1002/jlac.19606290113 10.1016/j.molcata.2013.07.005 10.1016/S0022-328X(96)06345-0 10.1021/jo00300a057 10.1002/jlac.19606290111 10.1016/S0022-328X(00)99208-8 10.1021/ja2099744 10.1016/S1381-1169(00)00059-5 10.1080/15321799508009638 10.1002/ange.19550671610 10.1016/j.apcata.2011.04.047 10.1016/j.ccr.2006.08.016 10.1021/cs200688g |
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| Snippet | The turnover frequency (TOF) and turnover number (TON) in styrene hydrogenation have been determined for catalytic systems based on Ni(acac)
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| SubjectTerms | Catalysis Chemistry Chemistry and Materials Science Physical Chemistry |
| Title | Functions of organoaluminum and proton donor compounds in the formation and functioning of nanosized Ziegler-type nickel-containing hydrogenation catalysts |
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