Layered Oxide Cathode‐Electrolyte Interface towards Na‐Ion Batteries: Advances and Perspectives

With the ever increasing demand for low‐cost and economic sustainable energy storage, Na‐ion batteries have received much attention for the application on large‐scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy...

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Published inChemistry, an Asian journal Vol. 17; no. 12; pp. e202200213 - n/a
Main Authors Lei, Zhou‐Quan, Guo, Yu‐Jie, Wang, En‐Hui, He, Wei‐Huan, Zhang, Yu‐Ying, Xin, Sen, Yin, Ya‐Xia, Guo, Yu‐Guo
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 15.06.2022
Subjects
Cathodes
Cathodic dissolution
Chemistry
Dissolution
Electrode materials
Electrolyte
Energy storage
Interface
Layered oxide cathode
Lithium-ion batteries
Na-ion batteries
Rechargeable batteries
Sodium
Sodium-ion batteries
Solvation
Stability
Storage batteries
Transition metals
Layered oxide cathode
Stability
Electrolyte
Interface
Na-ion batteries
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Abstract With the ever increasing demand for low‐cost and economic sustainable energy storage, Na‐ion batteries have received much attention for the application on large‐scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na+ ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li‐ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs. This review summarizes the current understanding of layered oxide cathode/electrolyte interphase in Na‐ion batteries (NIBs) and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.
AbstractList With the ever increasing demand for low‐cost and economic sustainable energy storage, Na‐ion batteries have received much attention for the application on large‐scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na+ ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li‐ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.
With the ever increasing demand for low‐cost and economic sustainable energy storage, Na‐ion batteries have received much attention for the application on large‐scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na+ ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li‐ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs. This review summarizes the current understanding of layered oxide cathode/electrolyte interphase in Na‐ion batteries (NIBs) and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.
With the ever increasing demand for low-cost and economic sustainable energy storage, Na-ion batteries have received much attention for the application on large-scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na+ ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li-ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.With the ever increasing demand for low-cost and economic sustainable energy storage, Na-ion batteries have received much attention for the application on large-scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na+ ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li-ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.
With the ever increasing demand for low-cost and economic sustainable energy storage, Na-ion batteries have received much attention for the application on large-scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li-ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.
With the ever increasing demand for low‐cost and economic sustainable energy storage, Na‐ion batteries have received much attention for the application on large‐scale energy storage for electric grids because of the worldwide distribution and natural abundance of sodium element, low solvation energy of Na + ion in the electrolyte and the low cost of Al as current collectors. Starting from a brief comparison with Li‐ion batteries, this review summarizes the current understanding of layered oxide cathode/electrolyte interphase in NIBs, and discusses the related degradation mechanisms, such as surface reconstruction and transition metal dissolution. Recent advances in constructing stable cathode electrolyte interface (CEI) on layered oxide cathode are systematically summarized, including surface modification of layered oxide cathode materials and formulation of electrolyte. Urgent challenges are detailed in order to provide insight into the imminent developments of NIBs.
Author Yin, Ya‐Xia
Lei, Zhou‐Quan
Wang, En‐Hui
Zhang, Yu‐Ying
He, Wei‐Huan
Guo, Yu‐Guo
Xin, Sen
Guo, Yu‐Jie
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  organization: Chinese Academy of Sciences (CAS)
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  fullname: He, Wei‐Huan
  organization: University of Chinese Academy of Sciences
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  surname: Zhang
  fullname: Zhang, Yu‐Ying
  organization: University of Chinese Academy of Sciences
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  surname: Xin
  fullname: Xin, Sen
  organization: University of Chinese Academy of Sciences
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  organization: University of Chinese Academy of Sciences
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  surname: Guo
  fullname: Guo, Yu‐Guo
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Keywords Layered oxide cathode
Stability
Electrolyte
Interface
Na-ion batteries
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Snippet With the ever increasing demand for low‐cost and economic sustainable energy storage, Na‐ion batteries have received much attention for the application on...
With the ever increasing demand for low-cost and economic sustainable energy storage, Na-ion batteries have received much attention for the application on...
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SubjectTerms Cathodes
Cathodic dissolution
Chemistry
Dissolution
Electrode materials
Electrolyte
Energy storage
Interface
Layered oxide cathode
Lithium-ion batteries
Na-ion batteries
Rechargeable batteries
Sodium
Sodium-ion batteries
Solvation
Stability
Storage batteries
Transition metals
Title Layered Oxide Cathode‐Electrolyte Interface towards Na‐Ion Batteries: Advances and Perspectives
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fasia.202200213
https://www.ncbi.nlm.nih.gov/pubmed/35560519
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https://www.proquest.com/docview/2664796317
Volume 17
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