An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries
Practical lithium–sulfur batteries are severely hindered by parasitic reactions between lithium metal anodes and soluble lithium polysulfide (LiPS) intermediates. The solvation structure of LiPSs is pivotal in dictating the reaction kinetics. Herein, an encapsulating LiPS electrolyte (EPSE) is propo...
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| Published in | Chem Vol. 8; no. 4; pp. 1083 - 1098 |
|---|---|
| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Inc
14.04.2022
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Practical lithium–sulfur batteries are severely hindered by parasitic reactions between lithium metal anodes and soluble lithium polysulfide (LiPS) intermediates. The solvation structure of LiPSs is pivotal in dictating the reaction kinetics. Herein, an encapsulating LiPS electrolyte (EPSE) is proposed to suppress parasitic reactions based on a nano-heterogeneous solvation structure design of LiPSs. In EPSE, with di-isopropyl sulfide (DIPS) as a co-solvent, soluble LiPSs are encapsulated into two concentric solvent shells with different solvating power and reduction stability. Reduction-stable DIPS in the outer solvent shell significantly suppresses the parasitic reactions between encapsulated LiPSs and lithium metal. A 1.2 Ah pouch cell under demanding conditions undergoes 103 cycles in the EPSE. This work provides two crucial criteria for constructing EPSE, that is, poor solvating power and high reduction stability of the solvent in outer solvent shell, and it opens up new frontiers in modulating the solvation structure of LiPSs toward long-cycling lithium–sulfur batteries.
[Display omitted]
•A nano-heterogeneous solvation structure of lithium polysulfides is investigated•An encapsulating LiPS electrolyte (EPSE) is designed for lithium–sulfur batteries•A 1.2 Ah pouch cell under demanding conditions undergoes 103 cycles in an EPSE•Two crucial criteria for constructing the EPSE are proposed
The pursuit of a zero-carbon and wireless society necessitates the development of high-energy-density and long-cycling batteries as the power source for portable electronics, electric vehicles, and so on. The lithium–sulfur battery is a promising high-energy-density battery system. However, parasitic reactions between lithium metal anodes and soluble lithium polysulfide (LiPS) intermediates severely hinder the lifespans of practical lithium–sulfur batteries, and rational electrolyte design is imperative. Herein, an encapsulating LiPS electrolyte (EPSE) is designed based on an insightful understanding of the solvation structure of LiPSs, which mitigates the parasitic reaction kinetics and significantly improves the cycle life of practical lithium–sulfur batteries. This opens up new frontiers in electrolyte design toward long-cycling lithium–sulfur batteries.
An encapsulating LiPS electrolyte (EPSE) is proposed for suppression of parasitic reactions based on a nano-heterogeneous solvation structure design of LiPSs. In the EPSE with di-isopropyl sulfide (DIPS) as a co-solvent, soluble LiPSs are encapsulated into two concentric solvent shells with different solvating power and reduction stability. Reduction-stable DIPS in the outer solvent shell significantly suppresses the parasitic reactions between encapsulated LiPSs and lithium metal. This work opens up new frontiers in electrolyte engineering toward long-cycling lithium–sulfur batteries. |
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| AbstractList | Practical lithium–sulfur batteries are severely hindered by parasitic reactions between lithium metal anodes and soluble lithium polysulfide (LiPS) intermediates. The solvation structure of LiPSs is pivotal in dictating the reaction kinetics. Herein, an encapsulating LiPS electrolyte (EPSE) is proposed to suppress parasitic reactions based on a nano-heterogeneous solvation structure design of LiPSs. In EPSE, with di-isopropyl sulfide (DIPS) as a co-solvent, soluble LiPSs are encapsulated into two concentric solvent shells with different solvating power and reduction stability. Reduction-stable DIPS in the outer solvent shell significantly suppresses the parasitic reactions between encapsulated LiPSs and lithium metal. A 1.2 Ah pouch cell under demanding conditions undergoes 103 cycles in the EPSE. This work provides two crucial criteria for constructing EPSE, that is, poor solvating power and high reduction stability of the solvent in outer solvent shell, and it opens up new frontiers in modulating the solvation structure of LiPSs toward long-cycling lithium–sulfur batteries.
[Display omitted]
•A nano-heterogeneous solvation structure of lithium polysulfides is investigated•An encapsulating LiPS electrolyte (EPSE) is designed for lithium–sulfur batteries•A 1.2 Ah pouch cell under demanding conditions undergoes 103 cycles in an EPSE•Two crucial criteria for constructing the EPSE are proposed
The pursuit of a zero-carbon and wireless society necessitates the development of high-energy-density and long-cycling batteries as the power source for portable electronics, electric vehicles, and so on. The lithium–sulfur battery is a promising high-energy-density battery system. However, parasitic reactions between lithium metal anodes and soluble lithium polysulfide (LiPS) intermediates severely hinder the lifespans of practical lithium–sulfur batteries, and rational electrolyte design is imperative. Herein, an encapsulating LiPS electrolyte (EPSE) is designed based on an insightful understanding of the solvation structure of LiPSs, which mitigates the parasitic reaction kinetics and significantly improves the cycle life of practical lithium–sulfur batteries. This opens up new frontiers in electrolyte design toward long-cycling lithium–sulfur batteries.
An encapsulating LiPS electrolyte (EPSE) is proposed for suppression of parasitic reactions based on a nano-heterogeneous solvation structure design of LiPSs. In the EPSE with di-isopropyl sulfide (DIPS) as a co-solvent, soluble LiPSs are encapsulated into two concentric solvent shells with different solvating power and reduction stability. Reduction-stable DIPS in the outer solvent shell significantly suppresses the parasitic reactions between encapsulated LiPSs and lithium metal. This work opens up new frontiers in electrolyte engineering toward long-cycling lithium–sulfur batteries. |
| Author | Zhang, Xue-Qiang Shi, Peng Hou, Li-Peng Li, Bo-Quan Zhang, Qiang Yao, Nan Jin, Cheng-Bin Huang, Jia-Qi Chen, Xiang |
| Author_xml | – sequence: 1 givenname: Li-Peng surname: Hou fullname: Hou, Li-Peng organization: Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China – sequence: 2 givenname: Xue-Qiang surname: Zhang fullname: Zhang, Xue-Qiang email: zhangxq@bit.edu.cn organization: Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, P.R. China – sequence: 3 givenname: Nan surname: Yao fullname: Yao, Nan organization: Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China – sequence: 4 givenname: Xiang surname: Chen fullname: Chen, Xiang organization: Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China – sequence: 5 givenname: Bo-Quan surname: Li fullname: Li, Bo-Quan organization: Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, P.R. China – sequence: 6 givenname: Peng surname: Shi fullname: Shi, Peng organization: Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China – sequence: 7 givenname: Cheng-Bin surname: Jin fullname: Jin, Cheng-Bin organization: Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China – sequence: 8 givenname: Jia-Qi surname: Huang fullname: Huang, Jia-Qi organization: Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, P.R. China – sequence: 9 givenname: Qiang surname: Zhang fullname: Zhang, Qiang email: zhang-qiang@mails.tsinghua.edu.cn organization: Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, P.R. China |
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| Keywords | encapsulating lithium polysulfide electrolyte solvent shell solvation structure di-isopropyl sulfide SDG7: Affordable and clean energy lithium–sulfur battery |
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| SubjectTerms | di-isopropyl sulfide encapsulating lithium polysulfide electrolyte lithium–sulfur battery solvation structure solvent shell |
| Title | An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries |
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