Self assembly and rheology of emulsions-mimicking food emulsion rheology
An investigation has been carried out to understand the microstructure of amino based surfactant (cocoyl glutamic acid, CGT) and viscoelastic properties of emulsions mimicking the food emulsion rheology. The structural modulation of the surfactant aggregates depends on the degree of neutralization,...
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Published in | Food Structure Vol. 1; no. 2; pp. 137 - 144 |
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Format | Journal Article |
Language | English |
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01.04.2014
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Abstract | An investigation has been carried out to understand the microstructure of amino based surfactant (cocoyl glutamic acid, CGT) and viscoelastic properties of emulsions mimicking the food emulsion rheology. The structural modulation of the surfactant aggregates depends on the degree of neutralization, temperature and oil concentration. Phase behaviour of the CGT surfactant system behaves similar to a short chain (C12EO8) (Aramaki & Khalid, 2004) or a long chain (C12EO25) (Rodriguez, Shigeta, & Kunieda, 2000) non-ionic surfactant systems, depending on the degree of neutralization. Krafft point of the CGT surfactant has been decreased with the addition of triethanolamine (TEA) and temperature. In presence of oil liquid crystal structure has been modified, which is due to the changing of the surfactant layer curvature (Kunieda, Umizu, & Aramaki, 2000). It is interesting to note that the I1 phase solubilizes large amount of oil. High viscosity with large amount of oil emulsions were obtained when the degree of neutralization, n=1.2. The decrease in viscosity with the oil content in the O/I1 emulsions is ascribed to the lower volume fraction of the continuous phase (I1 phase). |
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AbstractList | An investigation has been carried out to understand the microstructure of amino based surfactant (cocoyl glutamic acid, CGT) and viscoelastic properties of emulsions mimicking the food emulsion rheology. The structural modulation of the surfactant aggregates depends on the degree of neutralization, temperature and oil concentration. Phase behaviour of the CGT surfactant system behaves similar to a short chain (C12EO8) (Aramaki & Khalid, 2004) or a long chain (C12EO25) (Rodriguez, Shigeta, & Kunieda, 2000) non-ionic surfactant systems, depending on the degree of neutralization. Krafft point of the CGT surfactant has been decreased with the addition of triethanolamine (TEA) and temperature. In presence of oil liquid crystal structure has been modified, which is due to the changing of the surfactant layer curvature (Kunieda, Umizu, & Aramaki, 2000). It is interesting to note that the I1 phase solubilizes large amount of oil. High viscosity with large amount of oil emulsions were obtained when the degree of neutralization, n=1.2. The decrease in viscosity with the oil content in the O/I1 emulsions is ascribed to the lower volume fraction of the continuous phase (I1 phase). |
Author | Alam, Mohammad Mydul Oshimura, Eiko Aramaki, Kenji Iemoto, Suzuka |
Author_xml | – sequence: 1 givenname: Mohammad Mydul surname: Alam fullname: Alam, Mohammad Mydul email: sm5023@cc.saga-u.ac.jp, mydulalam@hotmail.com organization: Department of Chemistry, Faculty of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502, Japan – sequence: 2 givenname: Suzuka surname: Iemoto fullname: Iemoto, Suzuka organization: Graduate School of Environment and Information Sciences, Yokohama National University, Tokiwadai 79-7, Hodogaya-ku, Yokohama 240-8501, Japan – sequence: 3 givenname: Kenji surname: Aramaki fullname: Aramaki, Kenji organization: Graduate School of Environment and Information Sciences, Yokohama National University, Tokiwadai 79-7, Hodogaya-ku, Yokohama 240-8501, Japan – sequence: 4 givenname: Eiko surname: Oshimura fullname: Oshimura, Eiko organization: Research Institute for Bioscience Products & Fine Chemicals, Ajinomoto Co., 1-1 Suzuki-cho, Kawasaki-ku, Kawasaki 210-8681, Japan |
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CitedBy_id | crossref_primary_10_5107_sccj_50_201 crossref_primary_10_1007_s00397_018_1096_6 crossref_primary_10_1016_j_colsurfa_2017_11_010 crossref_primary_10_1016_j_colsurfa_2017_07_037 crossref_primary_10_5650_jos_ess15052 crossref_primary_10_1016_j_colsurfa_2017_08_035 crossref_primary_10_3390_foods12183483 |
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