In situ hydrothermal synthesis of dysprosium(III) single-molecule magnet with lanthanide salt as catalyst
A family of six dinuclear lanthanide complexes have been obtained via in situ hydrothermal synthesis with lanthanide ions as catalyst. These six complexes are formulated as [Ln(2)(3-Htzba)(2)(3-tzba)(2)(H(2)O)(8)]·4H(2)O [Ln = Gd, 1; Dy, 2; Eu, 3; Tb, 4; Sm, 5; Er, 6; 3-H(2)tzba = 3-(1H-tetrazol-5-y...
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| Published in | Dalton transactions : an international journal of inorganic chemistry Vol. 41; no. 19; pp. 5816 - 5823 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
21.05.2012
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| Abstract | A family of six dinuclear lanthanide complexes have been obtained via in situ hydrothermal synthesis with lanthanide ions as catalyst. These six complexes are formulated as [Ln(2)(3-Htzba)(2)(3-tzba)(2)(H(2)O)(8)]·4H(2)O [Ln = Gd, 1; Dy, 2; Eu, 3; Tb, 4; Sm, 5; Er, 6; 3-H(2)tzba = 3-(1H-tetrazol-5-yl)benzoic acid]. The magnetic investigations show that complex 2 behaves as a single-molecule magnet (SMM) with a quantum relaxation time of ~10(-2) s. |
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| AbstractList | A family of six dinuclear lanthanide complexes have been obtained via in situ hydrothermal synthesis with lanthanide ions as catalyst. These six complexes are formulated as [Ln(2)(3-Htzba)(2)(3-tzba)(2)(H(2)O)(8)]·4H(2)O [Ln = Gd, 1; Dy, 2; Eu, 3; Tb, 4; Sm, 5; Er, 6; 3-H(2)tzba = 3-(1H-tetrazol-5-yl)benzoic acid]. The magnetic investigations show that complex 2 behaves as a single-molecule magnet (SMM) with a quantum relaxation time of ~10(-2) s. |
| Author | Deng, Hong Li, Guizhu Peng, Guo Liang, Li Powell, Annie K Lan, Yanhua |
| Author_xml | – sequence: 1 givenname: Li surname: Liang fullname: Liang, Li organization: School of Chemistry & Environment, South China Normal University; Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou 510006, P. R. China – sequence: 2 givenname: Guo surname: Peng fullname: Peng, Guo – sequence: 3 givenname: Guizhu surname: Li fullname: Li, Guizhu – sequence: 4 givenname: Yanhua surname: Lan fullname: Lan, Yanhua – sequence: 5 givenname: Annie K surname: Powell fullname: Powell, Annie K – sequence: 6 givenname: Hong surname: Deng fullname: Deng, Hong |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22441758$$D View this record in MEDLINE/PubMed |
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| Title | In situ hydrothermal synthesis of dysprosium(III) single-molecule magnet with lanthanide salt as catalyst |
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