Light hydrocarbon geochemistry of crude oils from Eastern Niger Delta
Geochemical evaluation of oil samples from the eastern part of the Niger Delta divided into western, eastern, and central sections of the study area was carried out for the characterization of their light hydrocarbons content in order to correlate oils from different parts. The hydrocarbons in the o...
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Published in | Petroleum science and technology Vol. 36; no. 19; pp. 1573 - 1581 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Abingdon
Taylor & Francis
02.10.2018
Taylor & Francis Ltd |
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Abstract | Geochemical evaluation of oil samples from the eastern part of the Niger Delta divided into western, eastern, and central sections of the study area was carried out for the characterization of their light hydrocarbons content in order to correlate oils from different parts. The hydrocarbons in the oil samples were determined using gas chromatographic (GC) technique. The results obtained showed that CPI, Pr/Ph, Pr/nC
17
, and Ph/nC
18
ratios ranged from 0.99-1.55, 2.19-4.79, 0.92-2.35, and 0.27-0.47, respectively. The Pr/nC
17
versus Ph/nC
18
plot showed that the oils were derived from terrestrial organic materials that were deposited under oxic to suboxic conditions. They are moderately matured with minimal effect of biodegradation on most of the oil samples although two of the oils showed relatively higher degradation. Both bivariate and multivariate plots of the light hydrocarbon ratios differentiated the western and central oils from the eastern oils. The classification of the oils into families was not based on origin but rather on post generative alterations that include reservoir conditions and possibly migration effects. The light hydrocarbon parameters identified can be used in the correlation tools. |
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AbstractList | Geochemical evaluation of oil samples from the eastern part of the Niger Delta divided into western, eastern, and central sections of the study area was carried out for the characterization of their light hydrocarbons content in order to correlate oils from different parts. The hydrocarbons in the oil samples were determined using gas chromatographic (GC) technique. The results obtained showed that CPI, Pr/Ph, Pr/nC
17
, and Ph/nC
18
ratios ranged from 0.99-1.55, 2.19-4.79, 0.92-2.35, and 0.27-0.47, respectively. The Pr/nC
17
versus Ph/nC
18
plot showed that the oils were derived from terrestrial organic materials that were deposited under oxic to suboxic conditions. They are moderately matured with minimal effect of biodegradation on most of the oil samples although two of the oils showed relatively higher degradation. Both bivariate and multivariate plots of the light hydrocarbon ratios differentiated the western and central oils from the eastern oils. The classification of the oils into families was not based on origin but rather on post generative alterations that include reservoir conditions and possibly migration effects. The light hydrocarbon parameters identified can be used in the correlation tools. Geochemical evaluation of oil samples from the eastern part of the Niger Delta divided into western, eastern, and central sections of the study area was carried out for the characterization of their light hydrocarbons content in order to correlate oils from different parts. The hydrocarbons in the oil samples were determined using gas chromatographic (GC) technique. The results obtained showed that CPI, Pr/Ph, Pr/nC17, and Ph/nC18 ratios ranged from 0.99–1.55, 2.19–4.79, 0.92–2.35, and 0.27–0.47, respectively. The Pr/nC17 versus Ph/nC18 plot showed that the oils were derived from terrestrial organic materials that were deposited under oxic to suboxic conditions. They are moderately matured with minimal effect of biodegradation on most of the oil samples although two of the oils showed relatively higher degradation. Both bivariate and multivariate plots of the light hydrocarbon ratios differentiated the western and central oils from the eastern oils. The classification of the oils into families was not based on origin but rather on post generative alterations that include reservoir conditions and possibly migration effects. The light hydrocarbon parameters identified can be used in the correlation tools. |
Author | Omotoye, S. Adepoju, A. Akinlua, A. Adekola, S. A. |
Author_xml | – sequence: 1 givenname: A. surname: Adepoju fullname: Adepoju, A. organization: Department of Geology, Obafemi Awolowo University – sequence: 2 givenname: S. A. surname: Adekola fullname: Adekola, S. A. organization: Department of Geology, Obafemi Awolowo University – sequence: 3 givenname: S. surname: Omotoye fullname: Omotoye, S. organization: Department of Geology, Obafemi Awolowo University – sequence: 4 givenname: A. surname: Akinlua fullname: Akinlua, A. email: aakinlua@oauife.edu.ng, geochemresearch@yahoo.com organization: Fossil Fuels and Environmental Geochemistry Group, Department of Chemistry, Obafemi Awolowo University |
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Cites_doi | 10.1016/S0146-6380(98)00039-4 10.4314/jmg.v40i1.18805 10.1306/02190300116 10.1016/0146-6380(92)90036-W 10.1038/physci233051a0 10.1111/j.1747-5457.2003.tb00019.x 10.1126/science.237.4814.514 10.1016/0016-7037(94)90513-4 10.1016/0016-7037(90)90156-F 10.1016/j.petrol.2005.12.003 10.1016/S0146-6380(97)00031-4 10.1016/j.pnsc.2008.02.015 10.1007/978-94-009-7361-9 10.1016/0016-7037(83)90143-6 10.1016/j.orggeochem.2004.04.005 10.1007/978-3-642-87813-8 |
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SubjectTerms | Biodegradation Bivariate analysis classification Crude oil eastern Niger Delta Gas chromatography Geochemistry Hydrocarbons light hydrocarbons Migration oil Organic materials Parameter identification post-generative alterations |
Title | Light hydrocarbon geochemistry of crude oils from Eastern Niger Delta |
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