Experimental determination of the enthalpy of formation of dibenzo- p-dioxin

The standard molar enthalpy of combustion of dibenzo- p -dioxin (DD) was measured at T= 298.15 K by static-bomb combustion calorimetry: ΔcHmo(cr) =−(5723.8 ± 1.4)kJ · mol−1. The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: ΔcrgHmo= (91.45 ± 0.76)kJ · mol−...

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Published inThe Journal of chemical thermodynamics Vol. 34; no. 3; pp. 385 - 390
Main Authors Pimenova, S.M., Melkhanova, S.V., Kolesov, V.P., Demyanov, P.I., Fedotov, A.N., Vorobieva, V.P.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.03.2002
Subjects
calorimetry
dibenzodioxins
enthalpies of combustion
enthalpies of formation
environmental protection
thermochemistry
calorimetry
enthalpies of combustion
environmental protection
thermochemistry
enthalpies of formation
dibenzodioxins
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Abstract The standard molar enthalpy of combustion of dibenzo- p -dioxin (DD) was measured at T= 298.15 K by static-bomb combustion calorimetry: ΔcHmo(cr) =−(5723.8 ± 1.4)kJ · mol−1. The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: ΔcrgHmo= (91.45 ± 0.76)kJ · mol−1. These values were used to derive the standard molar enthalpies of formation of DD in the crystalline and gaseous states: ΔfHmo(cr) =−(141.6 ± 2.1)kJ · mol−1and ΔfHmo(g) =−(50.1 ± 2.2)kJ · mol−1. The specially obtained sample of DD of high purity {mole fraction x= (0.9999 ± 0.0001)} was used in all measurements.
AbstractList The standard molar enthalpy of combustion of dibenzo- p -dioxin (DD) was measured at T= 298.15 K by static-bomb combustion calorimetry: ΔcHmo(cr) =−(5723.8 ± 1.4)kJ · mol−1. The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: ΔcrgHmo= (91.45 ± 0.76)kJ · mol−1. These values were used to derive the standard molar enthalpies of formation of DD in the crystalline and gaseous states: ΔfHmo(cr) =−(141.6 ± 2.1)kJ · mol−1and ΔfHmo(g) =−(50.1 ± 2.2)kJ · mol−1. The specially obtained sample of DD of high purity {mole fraction x= (0.9999 ± 0.0001)} was used in all measurements.
Author Fedotov, A.N.
Kolesov, V.P.
Demyanov, P.I.
Melkhanova, S.V.
Pimenova, S.M.
Vorobieva, V.P.
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  organization: Institute of Chemical Physics RAN, Kosygina 4, Moscow 117977, Russia
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Cites_doi 10.1016/0040-6031(95)02310-X
10.1021/ja01563a044
10.1351/pac199668122339
10.1016/0040-6031(82)87008-1
10.1021/je980238r
10.1070/MC1999v009n04ABEH001074
10.1016/0045-6535(94)90056-6
10.1006/jcht.2000.0790
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Keywords calorimetry
enthalpies of combustion
environmental protection
thermochemistry
enthalpies of formation
dibenzodioxins
Language English
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Snippet The standard molar enthalpy of combustion of dibenzo- p -dioxin (DD) was measured at T= 298.15 K by static-bomb combustion calorimetry: ΔcHmo(cr) =−(5723.8 ±...
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SubjectTerms calorimetry
dibenzodioxins
enthalpies of combustion
enthalpies of formation
environmental protection
thermochemistry
Title Experimental determination of the enthalpy of formation of dibenzo- p-dioxin
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