Enhanced visible light-driven photocatalytic performance of Zr doped CeO2 nanoparticles

In this study, pristine and Zr-doped CeO 2 nanoparticles with chemical formula Ce 1−x Zr x O 2 (x = 0, 0.05, 0.075 and 0.1) have been prepared through facile hydrothermal process. The influence of Zr doping on the microstructure, thermal, optical and photocatalytic properties of CeO 2 was systematic...

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Published inJournal of materials science. Materials in electronics Vol. 30; no. 9; pp. 8291 - 8300
Main Authors Majeed Khan, M. A., Khan, Wasi, Naziruddin Khan, M., Alhazaa, Abdulaziz N.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.05.2019
Springer Nature B.V
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Abstract In this study, pristine and Zr-doped CeO 2 nanoparticles with chemical formula Ce 1−x Zr x O 2 (x = 0, 0.05, 0.075 and 0.1) have been prepared through facile hydrothermal process. The influence of Zr doping on the microstructure, thermal, optical and photocatalytic properties of CeO 2 was systematically explored through various analytical techniques. Analysis of the XRD data reveals cubic fluorite structure of the samples with average crystallite size of 12, 15, 21 and 30 nm respectively for different Zr doping. The optical properties of the nanoparticles were studied through UV–visible absorption and photoluminescence (PL) spectroscopy. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy measurements were performed to examine the chemical state and microstructure of the synthesized materials. The functional groups and mode of vibrations have been identified by the Fourier transform infrared (FTIR) spectroscopy. A reduction in the optical band gap of CeO 2 (from 3.25 to 3.10 eV) is observed on systematic Zr doping. In addition, significant enhancement in the photocatalytic performance is also noticed for the doped samples (92.2%) as compared to the pristine one (68.7%) for the degradation of methylene blue (MB) dye under visible light irradiation.
AbstractList In this study, pristine and Zr-doped CeO 2 nanoparticles with chemical formula Ce 1−x Zr x O 2 (x = 0, 0.05, 0.075 and 0.1) have been prepared through facile hydrothermal process. The influence of Zr doping on the microstructure, thermal, optical and photocatalytic properties of CeO 2 was systematically explored through various analytical techniques. Analysis of the XRD data reveals cubic fluorite structure of the samples with average crystallite size of 12, 15, 21 and 30 nm respectively for different Zr doping. The optical properties of the nanoparticles were studied through UV–visible absorption and photoluminescence (PL) spectroscopy. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy measurements were performed to examine the chemical state and microstructure of the synthesized materials. The functional groups and mode of vibrations have been identified by the Fourier transform infrared (FTIR) spectroscopy. A reduction in the optical band gap of CeO 2 (from 3.25 to 3.10 eV) is observed on systematic Zr doping. In addition, significant enhancement in the photocatalytic performance is also noticed for the doped samples (92.2%) as compared to the pristine one (68.7%) for the degradation of methylene blue (MB) dye under visible light irradiation.
In this study, pristine and Zr-doped CeO2 nanoparticles with chemical formula Ce1−xZrxO2 (x = 0, 0.05, 0.075 and 0.1) have been prepared through facile hydrothermal process. The influence of Zr doping on the microstructure, thermal, optical and photocatalytic properties of CeO2 was systematically explored through various analytical techniques. Analysis of the XRD data reveals cubic fluorite structure of the samples with average crystallite size of 12, 15, 21 and 30 nm respectively for different Zr doping. The optical properties of the nanoparticles were studied through UV–visible absorption and photoluminescence (PL) spectroscopy. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy measurements were performed to examine the chemical state and microstructure of the synthesized materials. The functional groups and mode of vibrations have been identified by the Fourier transform infrared (FTIR) spectroscopy. A reduction in the optical band gap of CeO2 (from 3.25 to 3.10 eV) is observed on systematic Zr doping. In addition, significant enhancement in the photocatalytic performance is also noticed for the doped samples (92.2%) as compared to the pristine one (68.7%) for the degradation of methylene blue (MB) dye under visible light irradiation.
Author Alhazaa, Abdulaziz N.
Majeed Khan, M. A.
Naziruddin Khan, M.
Khan, Wasi
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Snippet In this study, pristine and Zr-doped CeO 2 nanoparticles with chemical formula Ce 1−x Zr x O 2 (x = 0, 0.05, 0.075 and 0.1) have been prepared through facile...
In this study, pristine and Zr-doped CeO2 nanoparticles with chemical formula Ce1−xZrxO2 (x = 0, 0.05, 0.075 and 0.1) have been prepared through facile...
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StartPage 8291
SubjectTerms Cerium oxides
Characterization and Evaluation of Materials
Chemical synthesis
Chemistry and Materials Science
Crystallites
Doping
Fluorite
Fourier transforms
Functional groups
Light irradiation
Materials Science
Methylene blue
Microstructure
Nanoparticles
Optical and Electronic Materials
Optical properties
Organic chemistry
Photocatalysis
Photoelectrons
Photoluminescence
Raman spectroscopy
Spectrum analysis
X ray photoelectron spectroscopy
Zirconium
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Title Enhanced visible light-driven photocatalytic performance of Zr doped CeO2 nanoparticles
URI https://link.springer.com/article/10.1007/s10854-019-01147-w
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