Chemical stress relaxation of ethylene-propylene copolymer rubber by heat and radiation
In an attempt to shorten the evaluation time for the deterioration under various conditions caused by chemical reactions, we tried to extend the time-temperature superposition principle for the stress relaxation of rubber. In the case of deterioration by radiation instead of by heat, a time-dose rat...
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Published in | Radiation physics and chemistry Vol. 16; no. 6; pp. 481 - 485 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
1980
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Abstract | In an attempt to shorten the evaluation time for the deterioration under various conditions caused by chemical reactions, we tried to extend the time-temperature superposition principle for the stress relaxation of rubber. In the case of deterioration by radiation instead of by heat, a time-dose rate reduction is proposed and the master curves obtained for chemical-stress relaxation of rubber. A new method which contains a numerical analysis of stress decay curves is proposed to obtain the rate of crosslinking and scission under irradiation for already crosslinked samples. |
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AbstractList | In an attempt to shorten the evaluation time for the deterioration under various conditions caused by chemical reactions, we tried to extend the time-temperature superposition principle for the stress relaxation of rubber. In the case of deterioration by radiation instead of by heat, a time-dose rate reduction is proposed and the master curves obtained for chemical-stress relaxation of rubber. A new method which contains a numerical analysis of stress decay curves is proposed to obtain the rate of crosslinking and scission under irradiation for already crosslinked samples. |
Author | Ito, Masayuki Okada, Sohei Kuriyama, Isamu |
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Cites_doi | 10.1002/pol.1948.120030509 10.1002/pol.1975.170131118 10.1021/ja01619a008 10.1002/andp.18932861110 10.1002/andp.18932861011 |
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References | Williams, Landel, Ferry (BIB3) 1955; 77 Tobolsky (BIB1) 1948; 3 Charlesby, Pinner (BIB7) 1954; A269 S. Private communication. Wiechert, Wiechert (BIB5) 1893; 50 Ono, Kaeriyama, Murakami (BIB6) 1975; 13 Tobolsky (BIB4) 1958; Vol. 2 Williams (10.1016/0146-5724(80)90195-8_BIB3) 1955; 77 Charlesby (10.1016/0146-5724(80)90195-8_BIB7) 1954; A269 Ono (10.1016/0146-5724(80)90195-8_BIB6) 1975; 13 Wiechert (10.1016/0146-5724(80)90195-8_BIB5_2) 1893; 50 Tobolsky (10.1016/0146-5724(80)90195-8_BIB1) 1948; 3 10.1016/0146-5724(80)90195-8_BIB2 Tobolsky (10.1016/0146-5724(80)90195-8_BIB4) 1958; Vol. 2 Wiechert (10.1016/0146-5724(80)90195-8_BIB5_1) 1893; 50 |
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