Three New Lanthanum Oxoantimonate(III) Halides: Synthesis and Crystal Structure of La5Cl3[SbO3]4, La2Sb12O19Br4 and La2Sb12O19I4

• Published in: Crystals (Basel) Vol. 13; no. 5; p. 731
• Main Authors: Locke, Ralf, Bozenhardt, Kim-Natalie, Goerigk, Felix, Schleid, Thomas
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01.05.2023
• Subjects: Aluminum; Anions; Crystal structure; crystal structures; Fluorides; Halides; Lanthanum; Lattice parameters; oxoantimonates(III); Oxygen atoms; Raman spectra; Single crystals; Spectrum analysis; Japan; Germany

It was possible to synthesize colorless single crystals of La5Cl3[SbO3]4 (block-shaped) as well as La2Sb12O19Br4 and La2Sb12O19I4 (both needle-shaped), representing three new compounds from the system of lanthanum oxoantimonate(III) halides, which have not been described in the literature before. La...