Potassium Fluoride Assisted Selective Acetylation of Alcohols with Acetic Acid
Potassium fluoride promotes the acetylation of primary and secondary alcohols with acetic acid in excellent yield. Phenols are not affected under this reaction conditions. The groups like double bond, chloro, methoxy, benzyloxy, thiol, and nitro remain unaffected.
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| Published in | Synthetic communications Vol. 34; no. 15; pp. 2849 - 2855 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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PHILADELPHIA
Taylor & Francis Group
2004
Taylor & Francis |
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| Abstract | Potassium fluoride promotes the acetylation of primary and secondary alcohols with acetic acid in excellent yield. Phenols are not affected under this reaction conditions. The groups like double bond, chloro, methoxy, benzyloxy, thiol, and nitro remain unaffected. |
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| AbstractList | Potassium fluoride promotes the acetylation of primary and secondary alcohols with acetic acid in excellent yield. Phenols are not affected under this reaction conditions. The groups like double bond, chloro, methoxy, benzyloxy, thiol, and nitro remain unaffected. |
| Author | Saikia, Anil K. Rama Raju, B. John Bosco, J. W. |
| Author_xml | – sequence: 1 givenname: J. W. surname: John Bosco fullname: John Bosco, J. W. organization: Department of Chemistry , Indian Institute of Technology Guwahati – sequence: 2 givenname: B. surname: Rama Raju fullname: Rama Raju, B. organization: Department of Chemistry , Indian Institute of Technology Guwahati – sequence: 3 givenname: Anil K. surname: Saikia fullname: Saikia, Anil K. email: asaikia@iitg.ernet.in organization: Department of Chemistry , Indian Institute of Technology Guwahati |
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| CitedBy_id | crossref_primary_10_1038_s41598_019_55778_4 crossref_primary_10_1002_chin_200452046 crossref_primary_10_1016_j_tet_2016_04_073 crossref_primary_10_1016_j_jorganchem_2012_07_023 |
| Cites_doi | 10.1002/0471220574 10.1021/jo00816a039 10.1039/cs9831200129 10.1021/ja00494a045 10.1002/anie.197805691 10.1055/s-1975-23714 10.1016/j.tetasy.2003.08.010 10.1016/S0040-4039(01)98652-6 10.1246/cl.1995.141 10.1039/a606484a 10.1055/s-1983-30271 10.1016/S0040-4020(02)00966-3 10.1039/a705687g 10.1080/00397919608004588 10.1021/cr60327a004 10.1021/ja00061a056 10.1021/cr00020a004 10.1021/ja00833a047 10.1016/S0040-4039(00)94179-0 10.1021/jo00077a064 10.1002/jps.2600720411 |
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| Issue | 15 |
| Keywords | acetylation ORGANIC-SYNTHESIS ACYLATION acetic acid potassium fluoride alcohols 4-DIALKYLAMINOPYRIDINES TRIBUTYLPHOSPHINE CATALYSTS CARBOXYLIC-ACIDS |
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| References | DAUBEN, WG (WOS:A1983RU12900008) 1983; 24 SCRIVEN, EFV (WOS:A1983QZ75200002) 1983; 12 MARSHALL, JL (WOS:A1970H473400015) 1970 ZHDANOV RI (WOS:000223820300019.23) 1975 BERTIN, J (WOS:A1974V129400048) 1974; 96 BARRETT AGM (WOS:000223820300019.2) 1997 OTERA, J (WOS:A1993LJ04700004) 1993; 93 BARBOUR AK (WOS:000223820300019.1) 1963; 3 CLARK, JH (WOS:A1980KU53100004) 1980; 80 VESLEY, GF (WOS:A1971K155200039) 1971; 36 Ishihara, K (WOS:000178488100004) 2002; 58 STEFANO S (WOS:000223820300019.17) 2003; 14 FRANKLIN AS (WOS:000223820300019.8) 1998; 15 YAKOBSON, GG (WOS:A1983QF80300001) 1983 CONNORS KA (WOS:000223820300019.5) 1983; 72 HORTON D (WOS:000223820300019.12) 1973; 5 HOFLE, G (WOS:A1978FP99100003) 1978; 17 VEDEJS, E (WOS:A1993ML30700064) 1993; 58 STORK, G (WOS:A1978GA89900045) 1978; 100 VEDEJS, E (WOS:A1993KY50600056) 1993; 115 FRANKLIN AS (WOS:000223820300019.9) 1999; 24 DANASCIMENTO MG (WOS:000223820300019.6) 1996; 26 GREENE TW (WOS:000223820300019.10) 1999 CIT62450009 CIT62450007 Barrett A. G.M. (CIT62450008) 1997 CIT62450011c CIT62450006a CIT62450012 CIT62450005a CIT62450006b CIT62450003 CIT62450004a CIT62450005b CIT62450006c CIT62450004b CIT62450002a CIT62450004c CIT62450001a CIT62450002b CIT62450001b CIT62450002c CIT62450010 CIT62450011a CIT62450001c CIT62450011b |
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| Snippet | Potassium fluoride promotes the acetylation of primary and secondary alcohols with acetic acid in excellent yield. Phenols are not affected under this reaction... |
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| SubjectTerms | Acetic acid Acetylation Alcohols Chemistry Chemistry, Organic Physical Sciences Potassium fluoride Science & Technology |
| Title | Potassium Fluoride Assisted Selective Acetylation of Alcohols with Acetic Acid |
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