Electroinitiated polymerization of maleic anhydride with 1,4-dimethylpyridiniumiodide—kinetics of polymerization

The polymerization of maleic anhydride was investigated under constant current electrolysis in a simple H-type divided cell with 1,4-dimethylpyridiniumiodide as supporting electrolyte. The polymer formation depends on polymerization time, current intensity and on the nature of the supporting electro...

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Published inPolymer (Guilford) Vol. 40; no. 11; pp. 3261 - 3264
Main Author Sahu, Uma S
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 01.05.1999
Elsevier
Subjects
Applied sciences
Electroinitiation
Exact sciences and technology
Kinetics
Physicochemistry of polymers
Polymerization
Polymers and radiations
Electroinitiation
Kinetics
Iminium compounds
Maleic anhydride polymer
Reaction mechanism
Rate constant
Experimental study
Electrochemical polymerization
Pyridine derivatives
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Abstract The polymerization of maleic anhydride was investigated under constant current electrolysis in a simple H-type divided cell with 1,4-dimethylpyridiniumiodide as supporting electrolyte. The polymer formation depends on polymerization time, current intensity and on the nature of the supporting electrolyte. The polarographic measurements showed that the reduction potential of the supporting electrolyte is less than that of the monomer or the solvent. The product of the electrolysis arising from the supporting electrolyte initiates the polymerization. The mechanism of polymerization is assumed to be an anionic one.
AbstractList The polymerization of maleic anhydride was investigated under constant current electrolysis in a simple H-type divided cell with 1,4-dimethylpyridiniumiodide as supporting electrolyte. The polymer formation depends on polymerization time, current intensity and on the nature of the supporting electrolyte. The polarographic measurements showed that the reduction potential of the supporting electrolyte is less than that of the monomer or the solvent. The product of the electrolysis arising from the supporting electrolyte initiates the polymerization. The mechanism of polymerization is assumed to be an anionic one.
Author Sahu, Uma S
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Cites_doi 10.1002/macp.1962.020550104
10.1002/macp.1974.021750506
10.1021/ja01619a060
10.1002/macp.1973.021700111
10.1002/macp.1977.021780118
10.1002/macp.1970.021370128
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Issue 11
Keywords Electroinitiation
Kinetics
Iminium compounds
Maleic anhydride polymer
Reaction mechanism
Rate constant
Experimental study
Electrochemical polymerization
Pyridine derivatives
Language English
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Bhadani, Prasad (BIB2) 1977; 178
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Braun, Pomakis (BIB9) 1974; 175
Schopov (10.1016/S0032-3861(98)00490-X_BIB7) 1970; 137
Lange (10.1016/S0032-3861(98)00490-X_BIB4) 1963; 1
Braun (10.1016/S0032-3861(98)00490-X_BIB9) 1974; 175
Zwiefel (10.1016/S0032-3861(98)00490-X_BIB8) 1973; 170
Bhadani (10.1016/S0032-3861(98)00490-X_BIB2) 1977; 178
10.1016/S0032-3861(98)00490-X_BIB5
Kosower (10.1016/S0032-3861(98)00490-X_BIB3) 1955; 77
Joshi (10.1016/S0032-3861(98)00490-X_BIB6) 1962; 55
10.1016/S0032-3861(98)00490-X_BIB1
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SubjectTerms Applied sciences
Electroinitiation
Exact sciences and technology
Kinetics
Physicochemistry of polymers
Polymerization
Polymers and radiations
Title Electroinitiated polymerization of maleic anhydride with 1,4-dimethylpyridiniumiodide—kinetics of polymerization
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