Synthesis of a Homologous Series of Trialkyl Arsines (C3-C12) and Applications of Arsenic Triiodide as a Synthetic Precursor
This work presents some modifications in the post-synthetic processing for a classical arsenic reagent: AsI3. In comparison with the widely used analog, the trichloride, arsenic triiodide presents several advantages such as low toxicity, air stability, and low volatility. It was used as a synthetic...
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Published in | Journal of the Brazilian Chemical Society Vol. 32; no. 4; pp. 912 - 916 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English Portuguese |
Published |
Sociedade Brasileira de Química
01.04.2021
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Subjects | |
Online Access | Get full text |
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Summary: | This work presents some modifications in the post-synthetic processing for a classical arsenic reagent: AsI3. In comparison with the widely used analog, the trichloride, arsenic triiodide presents several advantages such as low toxicity, air stability, and low volatility. It was used as a synthetic precursor in the preparation of a variety of arsenic(III) derivatives like arsines, arsenites, and thioarsenites. Besides that, AsI3 was submitted to a diversity-oriented Grignard reaction in the preparation of a homologous series of trialkyl arsines ranging from AsC3H9 to AsC12H27. The series was analyzed by comprehensive two-dimensional gas chromatography coupled with time-of-flight mass spectrometry to provide a trialkyl arsines library that can be used for the direct analysis of natural samples. |
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ISSN: | 0103-5053 1678-4790 1678-4790 |
DOI: | 10.21577/0103-5053.20200242 |