Anion-dependent dysprosium() cluster single-molecule magnets

• Published in: New journal of chemistry Vol. 47; no. 4; pp. 18849 - 18855
• Main Authors: Liu, Cai-Ming, Hao, Xiang
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 16.10.2023
• Subjects: Anions; Carbon dioxide; Carbonyls; Chlorides; Clusters; Condensates; Dysprosium; Imines; Ligands; Magnets

A new Schiff base ligand, which is formed by the condensation reaction of 5-fluorosalicylaldehyde and pyrimidine-4-carbonyl hydrazide {H 2 L Schiff = ( E )- N ′-(5-fluoro-2-hydroxybenzylidene)pyrimidine-4-carbohydrazide}, was made to react with different dysprosium( iii ) salts in an alkaline soluti...