Energy-transfer photocatalysis for Minisci C-H (amino)alkylation of heteroarenes using oxime esters as dual-role reagents

• Published in: ORGANIC CHEMISTRY FRONTIERS Vol. 11; no. 18; pp. 5122 - 5129
• Main Authors: Xu, Jun, Zhang, Yuru, Xu, Ruiyuan, Wang, Yuxin, Shen, Jiabin, Li, Wanmei
• Format: Journal Article
• Language: English
• Published: CAMBRIDGE Royal Soc Chemistry 10.09.2024; Royal Society of Chemistry
• Subjects: Alkenes; Alkylation; Amino acids; Carboxylic acids; Chemistry; Chemistry, Organic; Energy transfer; Esters; Oxidants; Oxidizing agents; Oxime esters; Photocatalysis; Physical Sciences; Reagents; Science & Technology; BORONIC ACIDS; BOND-DISSOCIATION ENERGIES; ALKYLATION; ARYLATION; CASCADE; RADICALS; MOLECULAR-OXYGEN

Utilization of oxime esters as bifunctional reagents in energy-transfer photocatalysis has received considerable attention. However, the reaction type is so far limited to the difunctionalization of alkenes. To confront this limitation and enrich Minisci-type chemistry, herein we have developed a gr...