Hydrothermal synthesis and crystal structure of a novel double-perovskite-type bismuth oxide with 3 : 1 ordering at the B-site

• Published in: New journal of chemistry Vol. 46; no. 8; pp. 3595 - 361
• Main Authors: Hossain, Khandaker Monower, Saiduzzaman, Md, Kumada, Nobuhiro, Takei, Takahiro, Yamane, Hisanori
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 21.02.2022
• Subjects: Bismuth oxides; Catalytic activity; Crystal structure; First principles; Hydrothermal crystal growth; Light irradiation; Low temperature; Perovskite structure; Perovskites; Photocatalysis; Photodegradation; Single crystals; Synthesis

A low-temperature hydrothermal method was successfully used to synthesize a novel bismuth oxide Ba 4 Bi 3 NaO 12 . Here, NaBiO 3 · n H 2 O was used as one of the starting materials. Single-crystal X-ray diffraction revealed the triclinic double-perovskite-type structure of the novel compound with a...