A possible channel effect of the organics adsorbed to the electrode surface on interfacial electron transfer in the alkaline Pb electrodeposition process
In this paper, the mechanism of electron transfer (ET) in alkaline lead electrodeposition at 353 K was put forward based on the lower cell voltage, weaker polarization, less negative shift of the cathode peak, and lower charge transfer resistance using 1-benzyl-3-carboxyl-pyridinium (BCP) chloride a...
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Published in | New journal of chemistry Vol. 45; no. 24; pp. 1831 - 1838 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Royal Society of Chemistry
28.06.2021
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Abstract | In this paper, the mechanism of electron transfer (ET) in alkaline lead electrodeposition at 353 K was put forward based on the lower cell voltage, weaker polarization, less negative shift of the cathode peak, and lower charge transfer resistance using 1-benzyl-3-carboxyl-pyridinium (BCP) chloride as an additive, compared with 1-benzyl-3-methyl-pyridinium (BMP) chloride and gelatin. Namely, BCP possesses a π-bond system and a terminal charged group, which captures the Pb(OH)
4
2−
species by complexation and tethers (see
207
Pb-NMR spectroscopy and Raman spectroscopy) the metal ion to the active site of the cathode surface. BCP's positive heteroaromatic ring is adsorbed on the negative cathode (see XPS), and then forms a metal-molecule-metal ion molecular-bridge. The molecular-bridge consisted of a coherent conjugated π-bond, opening a channel for interfacial ET as the delocalization of the π-bond electron. The π-bond system of BCP can improve the ET facilitation compared with the δ bond system of BMP, and the ET resistance was reduced and the cell voltage was decreased relatively. Additives that can coordinate to the metal ion species and form a coherent conjugated system are considered to be used in industrial hydrometallurgy. The smoothing mechanism of the additive to the deposited product is also clarified at the same time.
A possible electron transfer channel in solid-liquid interface. |
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AbstractList | In this paper, the mechanism of electron transfer (ET) in alkaline lead electrodeposition at 353 K was put forward based on the lower cell voltage, weaker polarization, less negative shift of the cathode peak, and lower charge transfer resistance using 1-benzyl-3-carboxyl-pyridinium (BCP) chloride as an additive, compared with 1-benzyl-3-methyl-pyridinium (BMP) chloride and gelatin. Namely, BCP possesses a π-bond system and a terminal charged group, which captures the Pb(OH)
4
2−
species by complexation and tethers (see
207
Pb-NMR spectroscopy and Raman spectroscopy) the metal ion to the active site of the cathode surface. BCP's positive heteroaromatic ring is adsorbed on the negative cathode (see XPS), and then forms a metal–molecule–metal ion molecular-bridge. The molecular-bridge consisted of a coherent conjugated π-bond, opening a channel for interfacial ET as the delocalization of the π-bond electron. The π-bond system of BCP can improve the ET facilitation compared with the δ bond system of BMP, and the ET resistance was reduced and the cell voltage was decreased relatively. Additives that can coordinate to the metal ion species and form a coherent conjugated system are considered to be used in industrial hydrometallurgy. The smoothing mechanism of the additive to the deposited product is also clarified at the same time. In this paper, the mechanism of electron transfer (ET) in alkaline lead electrodeposition at 353 K was put forward based on the lower cell voltage, weaker polarization, less negative shift of the cathode peak, and lower charge transfer resistance using 1-benzyl-3-carboxyl-pyridinium (BCP) chloride as an additive, compared with 1-benzyl-3-methyl-pyridinium (BMP) chloride and gelatin. Namely, BCP possesses a π-bond system and a terminal charged group, which captures the Pb(OH) 4 2− species by complexation and tethers (see 207 Pb-NMR spectroscopy and Raman spectroscopy) the metal ion to the active site of the cathode surface. BCP's positive heteroaromatic ring is adsorbed on the negative cathode (see XPS), and then forms a metal-molecule-metal ion molecular-bridge. The molecular-bridge consisted of a coherent conjugated π-bond, opening a channel for interfacial ET as the delocalization of the π-bond electron. The π-bond system of BCP can improve the ET facilitation compared with the δ bond system of BMP, and the ET resistance was reduced and the cell voltage was decreased relatively. Additives that can coordinate to the metal ion species and form a coherent conjugated system are considered to be used in industrial hydrometallurgy. The smoothing mechanism of the additive to the deposited product is also clarified at the same time. A possible electron transfer channel in solid-liquid interface. In this paper, the mechanism of electron transfer (ET) in alkaline lead electrodeposition at 353 K was put forward based on the lower cell voltage, weaker polarization, less negative shift of the cathode peak, and lower charge transfer resistance using 1-benzyl-3-carboxyl-pyridinium (BCP) chloride as an additive, compared with 1-benzyl-3-methyl-pyridinium (BMP) chloride and gelatin. Namely, BCP possesses a π-bond system and a terminal charged group, which captures the Pb(OH)42− species by complexation and tethers (see 207Pb-NMR spectroscopy and Raman spectroscopy) the metal ion to the active site of the cathode surface. BCP's positive heteroaromatic ring is adsorbed on the negative cathode (see XPS), and then forms a metal–molecule–metal ion molecular-bridge. The molecular-bridge consisted of a coherent conjugated π-bond, opening a channel for interfacial ET as the delocalization of the π-bond electron. The π-bond system of BCP can improve the ET facilitation compared with the δ bond system of BMP, and the ET resistance was reduced and the cell voltage was decreased relatively. Additives that can coordinate to the metal ion species and form a coherent conjugated system are considered to be used in industrial hydrometallurgy. The smoothing mechanism of the additive to the deposited product is also clarified at the same time. |
Author | Ma, Chun-Ze Liu, Xin-Jie Tang, Guang-Shi Wan, Kang-Ni Pan, Jun-Qing |
AuthorAffiliation | Guangxi University of Science and Technology State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology |
AuthorAffiliation_xml | – name: Beijing University of Chemical Technology – name: State Key Laboratory of Chemical Resource Engineering – name: Guangxi University of Science and Technology |
Author_xml | – sequence: 1 givenname: Xin-Jie surname: Liu fullname: Liu, Xin-Jie – sequence: 2 givenname: Guang-Shi surname: Tang fullname: Tang, Guang-Shi – sequence: 3 givenname: Jun-Qing surname: Pan fullname: Pan, Jun-Qing – sequence: 4 givenname: Chun-Ze surname: Ma fullname: Ma, Chun-Ze – sequence: 5 givenname: Kang-Ni surname: Wan fullname: Wan, Kang-Ni |
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Snippet | In this paper, the mechanism of electron transfer (ET) in alkaline lead electrodeposition at 353 K was put forward based on the lower cell voltage, weaker... |
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SubjectTerms | Additives Cathodes Cathodic polarization Charge transfer Electric potential Electrode polarization Electrodeposition Electron transfer Electrons Gelatin Hydrometallurgy Lead isotopes Metal ions NMR spectroscopy Raman spectroscopy Spectrum analysis Voltage |
Title | A possible channel effect of the organics adsorbed to the electrode surface on interfacial electron transfer in the alkaline Pb electrodeposition process |
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