Proton conductivities of four low dimensional MOFs: affected by the amount of chelated ligands

• Published in: CrystEngComm Vol. 23; no. 29; pp. 516 - 5115
• Main Authors: Zhou, Chuan-Cong, Liu, Hou-Ting, Ding, Li, Lu, Jing, Wang, Su-Na, Li, Yun-Wu
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 07.08.2021
• Subjects: Cations; Conductivity; Coordination; Crystal structure; Crystallography; Hydrogen bonds; Infrared spectroscopy; Ligands; Membranes; Metal ions; Metal-organic frameworks; Moisture content; Molecular structure; Nickel compounds; Nicotinic acid; Protons; Water absorption; Water chemistry

Four low dimensional MOFs, {[Mn 3 (L) 2 (bipy) 2 ]} n ( 1 ), {[Mn 3 (L) 2 (phen) 2 ]} n ( 2 ), {[Co 3 (L) 2 (phen)(H 2 O) 8 ]·4H 2 O} n ( 3 ) and {[Ni 3 (L) 2 (H 2 O) 12 ]·4H 2 O} n ( 4 ) (H 3 L = 5-(3′,5′-dicarboxyphenyl) nicotinic acid; bipy = 2,2′-bipyridine; phen = phenanthroline) have been synt...