Equivalent cation-tuning to realize a new Ce() fluoride with excellent comprehensive nonlinear optical performances

• Published in: Inorganic chemistry frontiers Vol. 11; no. 22; pp. 813 - 8138
• Main Authors: Zhang, Bei-Bei, Gao, Wen-Ye, Xu, Wei, Ma, Liang, Liu, Wenlong, Tang, Ru-Ling, Guo, Sheng-Ping
• Format: Journal Article
• Language: English
• Published: London Royal Society of Chemistry 05.11.2024
• Subjects: Cations; Cerium; Laser damage; Metal fluorides; Nonlinear optics; Optical properties; Potassium phosphates; Second harmonic generation; Silver gallium sulfide; Yield point

Exploring nonlinear optical (NLO) halide materials has become a hot research field owing to their diverse structures and excellent optical properties. In this paper, a new inorganic tetravalent cerium fluoride NH 4 Ce 3 F 13 was obtained. It crystallizes in the polar space group of Pmc 2 1 and exhib...