The supramolecular frameworks and electrocatalytic properties of two new structurally diverse tertiary phosphane-appended nickel() and copper() thiosquarates

• Published in: CrystEngComm Vol. 25; no. 48; pp. 6822 - 6836
• Main Authors: Srivastava, Devyani, Kushwaha, Aparna, Kociok-Köhn, Gabriele, Gosavi, Suresh W, Chauhan, Ratna, Kumar, Abhinav, Muddassir, Mohd
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 11.12.2023
• Subjects: Chelation; Coordination; Copper; Density functional theory; Dichloromethane; Electrocatalysts; Electrons; Ethane; Hydrogen evolution reactions; Ligands; Nickel; Oxygen; Phosphorus; Quantum theory; Single crystals; Solid phases; Sulfur; Supramolecular frameworks; Surface analysis (chemical)

In this study, two new heteroleptic complexes with compositions [Ni(mtsq) 1.85 Cl 0.15 (dppe)](CH 2 Cl 2 ) 0.06 (CH 3 OH) 0.09 ( Ni-mtsq ) and [Cu(mtsq)(PPh 3 ) 2 ] ( Cu-mtsq ) (dppe = 1,2-bis-(diphenylphosphino)ethane; PPh 3 = triphenylphosphane and mtsq = 3-ethoxycyclobutenedione-4-thiolate) have...