Structure-property-performance relationship of vanadium- and manganese-based metal-organic frameworks and their derivatives for energy storage and conversion applications

Energy crises are currently the main challenges for human life. Promising solutions are expected from research on novel materials with a wide range of functional benefits. The new family of materials, known as metal-organic frameworks (MOFs), with coordination bonds between a metal and organic matte...

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Published inJournal of materials chemistry. A, Materials for energy and sustainability Vol. 12; no. 19; pp. 11149 - 11175
Main Authors Abazari, Reza, Sanati, Soheila, Nanjundan, Ashok Kumar, Wang, Qiyou, Dubal, Deepak P, Liu, Min
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 14.05.2024
Subjects
Crystals
Energy storage
Functional materials
Heavy metals
Hybrids
Manganese
Metal-organic frameworks
Metals
Organic matter
Oxidation
Porosity
Transition metals
Vanadium
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Abstract Energy crises are currently the main challenges for human life. Promising solutions are expected from research on novel materials with a wide range of functional benefits. The new family of materials, known as metal-organic frameworks (MOFs), with coordination bonds between a metal and organic matter as the center atom and ligand, respectively, are an exciting class of such functional materials. MOFs represent inorganic-organic hybrids of crystals, making them beneficial for different applications. In the past few years, several attempts have been made to modify pristine MOFs and achieve better characteristics, including a larger surface area, greater availability of active sites, highly stable materials, and improved transport and diffusion of mass. The present review summarizes MOFs containing vanadium and manganese, including multi-metallic materials, composites, and derivatives. It focuses on the structure, porosity, and stability and their impact on energy storage and conversion applications. Each MOF type containing vanadium and manganese is examined to highlight the association of porous structures and characteristics. This review will further provide a deep understanding and transparent insights into the functions of MOFs and their suitability for certain applications. Other interested researchers are recommended to examine material optimization and synthesis of various vanadium and manganese-based MOFs that are more stable while also showing higher capacity. Vanadium and manganese-MOFs have many different oxidation states that are useful for energy-related applications, and their comprehensive review in comparison with other first row transition metals has not been carried out yet. The current review discusses on vanadium- and manganese-based metal-organic frameworks and their derivatives for energy storage and conversion applications along with the potential future advancements in these fields.
AbstractList Energy crises are currently the main challenges for human life. Promising solutions are expected from research on novel materials with a wide range of functional benefits. The new family of materials, known as metal–organic frameworks (MOFs), with coordination bonds between a metal and organic matter as the center atom and ligand, respectively, are an exciting class of such functional materials. MOFs represent inorganic–organic hybrids of crystals, making them beneficial for different applications. In the past few years, several attempts have been made to modify pristine MOFs and achieve better characteristics, including a larger surface area, greater availability of active sites, highly stable materials, and improved transport and diffusion of mass. The present review summarizes MOFs containing vanadium and manganese, including multi-metallic materials, composites, and derivatives. It focuses on the structure, porosity, and stability and their impact on energy storage and conversion applications. Each MOF type containing vanadium and manganese is examined to highlight the association of porous structures and characteristics. This review will further provide a deep understanding and transparent insights into the functions of MOFs and their suitability for certain applications. Other interested researchers are recommended to examine material optimization and synthesis of various vanadium and manganese-based MOFs that are more stable while also showing higher capacity. Vanadium and manganese-MOFs have many different oxidation states that are useful for energy-related applications, and their comprehensive review in comparison with other first row transition metals has not been carried out yet.
Energy crises are currently the main challenges for human life. Promising solutions are expected from research on novel materials with a wide range of functional benefits. The new family of materials, known as metal-organic frameworks (MOFs), with coordination bonds between a metal and organic matter as the center atom and ligand, respectively, are an exciting class of such functional materials. MOFs represent inorganic-organic hybrids of crystals, making them beneficial for different applications. In the past few years, several attempts have been made to modify pristine MOFs and achieve better characteristics, including a larger surface area, greater availability of active sites, highly stable materials, and improved transport and diffusion of mass. The present review summarizes MOFs containing vanadium and manganese, including multi-metallic materials, composites, and derivatives. It focuses on the structure, porosity, and stability and their impact on energy storage and conversion applications. Each MOF type containing vanadium and manganese is examined to highlight the association of porous structures and characteristics. This review will further provide a deep understanding and transparent insights into the functions of MOFs and their suitability for certain applications. Other interested researchers are recommended to examine material optimization and synthesis of various vanadium and manganese-based MOFs that are more stable while also showing higher capacity. Vanadium and manganese-MOFs have many different oxidation states that are useful for energy-related applications, and their comprehensive review in comparison with other first row transition metals has not been carried out yet. The current review discusses on vanadium- and manganese-based metal-organic frameworks and their derivatives for energy storage and conversion applications along with the potential future advancements in these fields.
Author Sanati, Soheila
Wang, Qiyou
Abazari, Reza
Dubal, Deepak P
Liu, Min
Nanjundan, Ashok Kumar
AuthorAffiliation Department of Chemistry
Central South University
Queensland University of Technology
School of Engineering and Centre for Future Materials
School of Chemistry & Physics
Hunan Joint International Research Center for Carbon Dioxide Resource Utilization
School of Physics
Faculty of Basic Sciences
University of Southern Queensland
University of Maragheh
State Key Laboratory of Powder Metallurgy
Centre for Materials Science
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  name: School of Engineering and Centre for Future Materials
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  name: Hunan Joint International Research Center for Carbon Dioxide Resource Utilization
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  name: Faculty of Basic Sciences
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Notes Prof. Deepak Dubal is currently working as Full Professor at Queensland University of Technology (QUT), Australia. He is a productive, well-cited, and multiplefellowship-winning scientist. His achievements are honoured by several prestigious fellowships such as Brain Korea-21 (South Korea-2011), Alexander von Humboldt (Germany-2012), Marie Curie (Spain-2014), and Australian Future Fellowship (Australia-2018). His research expertise lies in the design and development of multifunctional materials for clean energy conversion and storage technologies with a special focus on supercapacitors, lithium-ion batteries, Li-ion capacitors, and electrochemical flow cells. In addition, his team is extending its research area in biomass valorisation and battery recycling, aiding circular economy and sustainable practices.
2
Dr Soheila Sanati obtained her PhD in Inorganic Chemistry at Azarbaijan Shahid Madani University (Iran) in February 2019. Her research interests mainly focus on the design, synthesis, and applications of layered double hydroxides and metal-organic framework-based nanostructured materials for energy storage and conversion, irradiation thermal treatment, renewable clean energy and environmental protection applications.
h
reduction and the resource utilization of perfluorocarbons.
index 69). His research focuses on electrocatalytic energy conversion, photo-electrocatalytic CO
Dr Reza Abazari obtained his MSc in Inorganic Chemistry from K. N. Toosi University of Technology (Iran) in 2012 and his PhD from Tarbiat Modares University in 2019. Currently, he is working as a Youth Research Professor at University of Maragheh, Iran. His research interests include the design and synthesis of nanostructured materials based on crystalline porous frameworks for electrochemical energy storage and photocatalytic applications.
Prof. Min Liu received his PhD (2010) from Chinese Academy of Sciences. In 2010-2015, he joined the University of Tokyo as a research fellow with Prof. Kazuhito Hashimoto and Prof. Kazunari Domen, separately. In 2015-2017, he joined the University of Toronto as a postdoctoral fellow with Prof. Edward Sargent. Since 2017, he has been working as a professor at Central South University. He has published more than 200 papers with over 21,000 citations
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Snippet Energy crises are currently the main challenges for human life. Promising solutions are expected from research on novel materials with a wide range of...
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SubjectTerms Crystals
Energy storage
Functional materials
Heavy metals
Hybrids
Manganese
Metal-organic frameworks
Metals
Organic matter
Oxidation
Porosity
Transition metals
Vanadium
Title Structure-property-performance relationship of vanadium- and manganese-based metal-organic frameworks and their derivatives for energy storage and conversion applications
URI https://www.proquest.com/docview/3054426819
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