Synthesis of renewable isoindolines from bio-based furfurals

• Published in: Green chemistry : an international journal and green chemistry resource : GC Vol. 25; no. 8; pp. 3297 - 335
• Main Authors: Xu, Feng, Li, Zao, Zhang, Li-Long, Liu, Shengqi, Li, Hu, Liao, Yuhe, Yang, Song
• Format: Journal Article
• Language: English
• Published: CAMBRIDGE Royal Soc Chemistry 24.04.2023; Royal Society of Chemistry
• Subjects: Adducts; Aromatic compounds; Catalysts; Chemistry; Chemistry, Multidisciplinary; Cycloaddition; Diels-Alder reactions; Green & Sustainable Science & Technology; Green chemistry; Ionic liquids; Liquid phases; Physical Sciences; Regioselectivity; Science & Technology; Science & Technology - Other Topics; Thermal stability; BIOMASS-DERIVED FURAN; 2,5-DIMETHYLFURAN; ETHYLENE; P-XYLENE; CONVERSION; CATALYZED REDUCTIVE ALKOXYLATION; ONE-POT; ACRYLIC-ACID; EFFICIENT; DIELS-ALDER CYCLOADDITION

Upgrading biomass-derived platforms to functionalized aromatics by a tandem Diels-Alder (DA) cycloaddition-aromatization strategy has attracted broad attention. However, three challenges exist: improving the equilibrium of DA cycloaddition, controlling the regioselectivity of DA adducts, and increas...