New pyrimidine-amide-tetrazole ligand derived polyoxometalate-based copper complexes as catalysts for sulfide-sulfoxide transformation and electrochemical sensors

• Published in: CrystEngComm Vol. 25; no. 2; pp. 325 - 332
• Main Authors: Lu, Jun-Jun, Lin, Hong-Yan, Liu, Qian-Qian, Liu, Xiao-Dong, Wang, Xiu-Li
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 22.05.2023
• Subjects: Anions; Catalysts; Chemical sensors; Copper compounds; Electrocatalysts; Infrared spectroscopy; Ligands; Oxidation; Polyoxometallates; Single crystals; Synthesis; Tetrazoles; X ray powder diffraction; X-ray diffraction
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/d3ce00269a

In this study, a new ligand, 5-(4-pyrimidinecarboxamido)-1 H -tetrazol (4-H 2 pat), was synthesized by connecting the pyrimidine group and tetrazole group through an amide bond for the first time, aiming to construct new POM-based metal-organic complexes (POMOCs). By using the ligand 4-H 2 pat, two...