New green energetic materials based on unsymmetrically substituted pyrazole-tetrazines and their hydroperchlorates

• Published in: New journal of chemistry Vol. 43; no. 47; pp. 18637 - 18646
• Main Authors: Yang, Zhen-Li, Wang, Zhen, Cao, Wen-li, Li, Tong, Yang, Jun-Qing, Zhang, Jian-Guo
• Format: Journal Article
• Language: English
• Published: CAMBRIDGE Royal Soc Chemistry 02.12.2019; Royal Society of Chemistry
• Subjects: Chemical analysis; Chemistry; Chemistry, Multidisciplinary; Computation; Crystallography; Detonation; Energetic materials; Enthalpy; Mass spectra; Parameter sensitivity; Physical Sciences; Pyrazole; Raw materials; Science & Technology; Single crystals; Stability analysis; Synthesis; Technology assessment; Thermal stability; TRANSITION; DENSITY; DESIGN; COMPLEXES; C LINKED TETRAZOLE; SALTS; DERIVATIVES

Five novel nitrogen-rich energetic materials were synthesized using 3,6-bis(3,5-dimethyl-pyrazole-1-yl)-1,2,4,5-tetrazine (BT) and 3,6-bis(pyrazole-1-yl)-1,2,4,5-tetrazine as raw materials. The materials were comprehensively characterized by single-crystal X-ray diffraction, FT-IR, mass spectra and...