Development of MOF-5-like ultra-microporous metal-squarate frameworks for efficient acetylene storage and separation

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 11; no. 39; pp. 2123 - 2121
• Main Authors: Li, Hai-Peng, Wang, Jia-Wen, Zhai, Quan-Guo
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 10.10.2023
• Subjects: Acetylene; Adsorption; Aqueous solutions; Flow rates; Hydrogen bonding; Hydrogen bonds; Metal-organic frameworks; Porosity; Separation; Transition metals; Zinc

Although MOF-5 and its related family members are landmark metal-organic frameworks (MOFs), they have large specific surface area and high porosity, which have long been a subject regarding their instability. The introduction of new inorganic building blocks, in addition to classical [Zn 4 O(COO) 6...