Sintering process as relevant parameter for Bi2O3 vaporization from ZnO-Bi2O3-based varistor ceramics

• Published in: Transactions of Nonferrous Metals Society of China Vol. 19; no. 6; pp. 1526 - 1532
• Main Author: 徐东 程晓农 严学华 徐红星 施利毅
• Format: Journal Article
• Language: English
• Published: 01.12.2009
• Subjects: 压敏陶瓷; 微观组织演变; 氧化锌; 烧结时间; 烧结温度; 烧结过程
• ISSN: 1003-6326
• DOI: 10.1016/S1003-6326(09)60064-9

The relationship between sintering process and vaporization of the Bi2O3 in ZnO-Bi2O3-based varistor ceramics was investigated. The phase and microstructure evolution during the sintering process were examined. The results show that the higher the sintering temperature or the longer the sintering time is, the more the Bi2O3 is volatilized. The heating rate has little effects on the Bi2O3 volatilized in ZnO-Bi2O3-based varistor ceramics. This is in accordance with the relative X-ray diffraction peak area ratio analysis. The results also show that the sintering temperature has the greatest impact on the vaporization of the Bi2O3, then followed by sintering time, and the effect of the heating rate is the minimum.