Developing a Bench-Scale Green Diboration Reaction toward Industrial Application

We report a new methodology for the organocatalytic diboration reaction using inexpensive, sustainable, nontoxic, commercially available halogen salts. This is an educative manuscript for the transformation of laboratory scale reactions into a sustainable approach of appeal to industry.

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Bibliographic Details
Published inSynthesis (Stuttgart) Vol. 49; no. 21; pp. 4775 - 4782
Main Authors Farre, Albert, Briggs, Rachel, Pubill-Ulldemolins, Cristina, Bonet, Amadeu
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 02.11.2017
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
boron chemistry
ORGANOCATALYTIC DIBORATION
ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
DIBORON COMPOUNDS
green chemistry
BORON CONJUGATE ADDITIONS
organocatalysis
LEWIS-BASE ADDUCTS
LITHIATION-BORYLATION
ASYMMETRIC INDUCTION
CATALYZED BETA-BORATION
PHARMACEUTICAL-INDUSTRY
ate complexes
STEREOCONTROLLED SYNTHESIS
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Summary:We report a new methodology for the organocatalytic diboration reaction using inexpensive, sustainable, nontoxic, commercially available halogen salts. This is an educative manuscript for the transformation of laboratory scale reactions into a sustainable approach of appeal to industry.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-0036-1590912