Microwave promoted Heck reactions using an oligo(ethylene glycol)-bound SCS palladacycle under thermomorphic conditions
Palladium catalyzed Heck couplings utilizing an air-stable, water-soluble oligo(ethylene glycol)-bound SCS palladacycle catalyst and microwave irradiation lead to formation of several cinnamic acid derivatives with reaction times of less than 1 hour. Such couplings of various aryl halides with alken...
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| Published in | Green chemistry : an international journal and green chemistry resource : GC Vol. 6; no. 6; pp. 280 - 285 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
01.01.2004
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Palladium catalyzed Heck couplings utilizing an air-stable, water-soluble oligo(ethylene glycol)-bound SCS palladacycle catalyst and microwave irradiation lead to formation of several cinnamic acid derivatives with reaction times of less than 1 hour. Such couplings of various aryl halides with alkene acceptors occur in an air atmosphere with aqueous and organic solvents are described. Recycling of the catalyst was accomplished using a 10% aqueous DMA-heptane thermomorphic system that was advantageously homogeneous during these microwave promoted reactions and biphasic during the catalyst recovery step. |
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| AbstractList | Palladium catalyzed Heck couplings utilizing an air-stable, water-soluble oligo(ethylene glycol)-bound SCS palladacycle catalyst and microwave irradiation lead to formation of several cinnamic acid derivatives with reaction times of less than 1 hour. Such couplings of various aryl halides with alkene acceptors occur in an air atmosphere with aqueous and organic solvents are described. Recycling of the catalyst was accomplished using a 10% aqueous DMA-heptane thermomorphic system that was advantageously homogeneous during these microwave promoted reactions and biphasic during the catalyst recovery step. |
| Author | Bergbreiter, David E. Furyk, Steven |
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| Title | Microwave promoted Heck reactions using an oligo(ethylene glycol)-bound SCS palladacycle under thermomorphic conditions |
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