Variability of Rhodium(III)-Catalyzed Reactions of Aromatic Oximes with Alkenes

• Published in: Synlett Vol. 31; no. 11; pp. 1117 - 1120
• Main Authors: Trifonova, Evgeniya A., Komarova, Alina A., Chusov, Denis, Perekalin, Dmitry S.
• Format: Journal Article
• Language: English
• Published: STUTTGART Thieme Medical Publishers 01.07.2020
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; FUNCTIONALIZATION; isoquinolines; C-H activation; ALLYLATION; ARENES; REGIOSELECTIVE SYNTHESIS; alkenes; oximes; rhodium catalysis; ACCESS

Acetophenone oxime reacts with various alkenes in the presence of the rhodium catalyst [Cp*RhCl (2) ] (2) (2.5 mol%; Cp* = pentamethylcyclopentadienyl) and 1,1,1,3,3,3-hexafluoropropan-2-ol as an important cosolvent. Styrene, aliphatic terminal alkenes, and strained cyclic alkenes gave the correspon...