Integrating Uranyl Complexes into Porous Organic Cages for Enhanced Photocatalytic Oxidation of A Mustard‐Gas Simulant

• Published in: European journal of inorganic chemistry Vol. 28; no. 21
• Main Authors: Hu, Bo‐wen, Jin, Wei, Huang, Zhi‐wei, Zhou, Zhi‐heng, Hu, Kong‐qiu, Yuan, Li‐yong, He, Hui‐bing, Shi, Wei‐qun, Mei, Lei
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 29.07.2025
• Subjects: Cages; calixresorcinarene; Catalysts; Catalytic activity; Catalytic oxidation; Contaminants; Mass transfer; Mustard gas; Oxidation; Photocatalysis; Photocatalysts; porous organic cages; post‐synthetic modification; uranyl

In this work, a new kind of uranyl‐based photocatalysts, i.e., uranyl‐modified porous organic cages, U@HPOCs, are prepared for the first time via a post‐synthetic modification (PSM) of preassembled porous organic cages (POCs) by uranyl sources. The successful integration of uranyl into U@HPOCs, as w...