An evaporation study of C76 by Knudsen cell mass spectrometry
The vapour pressure of pure C76 and its sublimation enthalpy have been determined by Knudsen cell mass spectrometry in the temperature range 637–911 K. The temperature–pressure equation is ln p(Pa) =(−22 806 ± 820)/T(K) + (24.52 ± 1.08). The mean sublimation enthalpy at 764 K is (190 ± 7) kJ/mol. T...
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| Published in | Rapid communications in mass spectrometry Vol. 12; no. 15; pp. 1028 - 1030 |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Chichester, UK
John Wiley & Sons, Ltd
15.08.1998
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| Online Access | Get full text |
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| Abstract | The vapour pressure of pure C76 and its sublimation enthalpy have been determined by Knudsen cell mass spectrometry in the temperature range 637–911 K. The temperature–pressure equation is ln p(Pa) =(−22 806 ± 820)/T(K) + (24.52 ± 1.08). The mean sublimation enthalpy at 764 K is (190 ± 7) kJ/mol. This value is lower than that, (222 ± 17) kJ/mol, determined by us previously from a mixture of higher fullerenes,1 confirming further that the mixture of higher fullerenes is not an ideal solid solution. © 1998 John Wiley & Sons, Ltd. |
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| AbstractList | The vapour pressure of pure C76 and its sublimation enthalpy have been determined by Knudsen cell mass spectrometry in the temperature range 637–911 K. The temperature–pressure equation is ln p(Pa) =(−22 806 ± 820)/T(K) + (24.52 ± 1.08). The mean sublimation enthalpy at 764 K is (190 ± 7) kJ/mol. This value is lower than that, (222 ± 17) kJ/mol, determined by us previously from a mixture of higher fullerenes,1 confirming further that the mixture of higher fullerenes is not an ideal solid solution. © 1998 John Wiley & Sons, Ltd. |
| Author | Borschevskii, Andrey Ya Eletskii, Alexander V. Sidorov, Lev N. Boltalina, Olga V. Bezmelnitsin, Valery N. Taylor, Roger Markov, Vitaliy Yu |
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| Snippet | The vapour pressure of pure C76 and its sublimation enthalpy have been determined by Knudsen cell mass spectrometry in the temperature range 637–911 K. The... |
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| Title | An evaporation study of C76 by Knudsen cell mass spectrometry |
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