Tribological modification of metal counterface by rubber
Sulphur vulcanizates of styrene-budadiene rubber (SBR) filled with 80 phr of silica were rubbed extensively against iron Armco or magnesium alloy (AZ 31), and chemical modification of the surface layer of metals studied. Secondary Ion Mass Spectrometer (s-SIMS) spectra revealed fragments containing...
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| Published in | Tribology letters Vol. 24; no. 2; pp. 115 - 118 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Dordrecht
Springer Nature B.V
01.11.2006
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Sulphur vulcanizates of styrene-budadiene rubber (SBR) filled with 80 phr of silica were rubbed extensively against iron Armco or magnesium alloy (AZ 31), and chemical modification of the surface layer of metals studied. Secondary Ion Mass Spectrometer (s-SIMS) spectra revealed fragments containing sulphur. Also Raman spectra, obtained with the surface focused confocal microscope, apart metal oxides, contained absorption peaks indicated on metal sulfides and sulfates. Depth of the modification, calculated from Atomic Force Microscope profiles of ion-etched samples (s-SIMS depth profiling) reached several tens of nanometers, what corresponds to several monolayers. The thickness of modified layer was higher for magnesium alloy, due to its higher electronegative character in comparison to iron. |
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| AbstractList | Sulphur vulcanizates of styrene-budadiene rubber (SBR) filled with 80 phr of silica were rubbed extensively against iron Armco or magnesium alloy (AZ 31), and chemical modification of the surface layer of metals studied. Secondary Ion Mass Spectrometer (s-SIMS) spectra revealed fragments containing sulphur. Also Raman spectra, obtained with the surface focused confocal microscope, apart metal oxides, contained absorption peaks indicated on metal sulfides and sulfates. Depth of the modification, calculated from Atomic Force Microscope profiles of ion-etched samples (s-SIMS depth profiling) reached several tens of nanometers, what corresponds to several monolayers. The thickness of modified layer was higher for magnesium alloy, due to its higher electronegative character in comparison to iron. |
| Author | Wiatrowski, M. Paryjczak, T. Grams, J. Bieliński, D. M. |
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| Cites_doi | 10.14314/polimery.2005.298 10.1002/app.11321 |
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| DOI | 10.1007/s11249-006-9044-5 |
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| References | D.M. Bieliński (9044_CR6) 2005; 50 9044_CR7 D.M. Bieliński (9044_CR5) 2002; 86 S. Płaza (9044_CR2) 1997 9044_CR1 9044_CR4 9044_CR3 |
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| SubjectTerms | Atomic force microscopes Atomic force microscopy Cast iron Depth profiling Electronegativity Magnesium alloys Magnesium base alloys Metal sulfides Microscopes Organic chemistry Raman spectra Rubber Secondary ion mass spectrometry Silicon dioxide Sulfur Surface layers Thickness Tribology |
| Title | Tribological modification of metal counterface by rubber |
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