Boosting the catalysis of cesium phosphomolybdate encapsulated in hierarchical porous UiO-66 by microenvironment modulation for epoxidation of alkenes

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 52; no. 4; pp. 14676 - 14685
• Main Authors: Hu, Dianwen, Miao, Songsong, Zhang, Pengfei, Wu, Siyuan, He, Yu-Peng, Meng, Qingwei
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 17.10.2023
• Subjects: Alkenes; Benzene; Butyl hydroperoxide; Catalysis; Catalytic activity; Cesium; Composite materials; Encapsulation; Epoxidation; Functional groups; Metal-organic frameworks; Modulation; Polyoxometallates; Stability; Substitution reactions

The chemical microenvironment of polyoxometalates (POMs) encapsulated in metal-organic frameworks (MOFs) presents a significant influence on their catalytic performance, which can be easily regulated by the linker functional group alteration or metal substitution in MOFs. Herein, a series of cesium...