Thermal and mechanical behavior of amorphous and semi-crystalline poly(vinylidene fluoride)/poly(methyl methacrylate) blends
Various PVDF/PMMA (poly(vinylidene fluoride)/poly(methyl methacrylate)) blends were selected for mechanical testing in compression. At low PVDF content (less than 50/50 w/w), the blends remain amorphous and PVDF and PMMA are fully miscible. In PVDF‐richer blends, PVDF crystallizes in part, leading t...
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Published in | Macromolecular symposia. Vol. 198; no. 1; pp. 103 - 116 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag
01.08.2003
WILEY‐VCH Verlag |
Subjects | |
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Abstract | Various PVDF/PMMA (poly(vinylidene fluoride)/poly(methyl methacrylate)) blends were selected for mechanical testing in compression. At low PVDF content (less than 50/50 w/w), the blends remain amorphous and PVDF and PMMA are fully miscible. In PVDF‐richer blends, PVDF crystallizes in part, leading to a PMMA‐enriched homogeneous amorphous phase. In this study, the degree of crystallinity was set at equilibrium by appropriate annealing of the samples before testing. Mechanical analysis was focused on the low deformation range, and especially on the yield region. Depending on the test temperature and blend composition, three types of response were identified, depending on whether plastic deformation is influenced: 1) by the PMMA secondary relaxation motions, 2) by the PVDF/PMMA glass transition motions, or 3) by the crystallite‐constrained PVDF chains. |
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AbstractList | Abstract
Various PVDF/PMMA (poly(vinylidene fluoride)/poly(methyl methacrylate)) blends were selected for mechanical testing in compression. At low PVDF content (less than 50/50 w/w), the blends remain amorphous and PVDF and PMMA are fully miscible. In PVDF‐richer blends, PVDF crystallizes in part, leading to a PMMA‐enriched homogeneous amorphous phase. In this study, the degree of crystallinity was set at equilibrium by appropriate annealing of the samples before testing. Mechanical analysis was focused on the low deformation range, and especially on the yield region. Depending on the test temperature and blend composition, three types of response were identified, depending on whether plastic deformation is influenced: 1) by the PMMA secondary relaxation motions, 2) by the PVDF/PMMA glass transition motions, or 3) by the crystallite‐constrained PVDF chains. Various PVDF/PMMA (poly(vinylidene fluoride)/poly(methyl methacrylate)) blends were selected for mechanical testing in compression. At low PVDF content (less than 50/50 w/w), the blends remain amorphous and PVDF and PMMA are fully miscible. In PVDF-richer blends, PVDF crystallizes in part, leading to a PMMA-enriched homogeneous amorphous phase. In this study, the degree of crystallinity was set at equilibrium by appropriate annealing of the samples before testing. Mechanical analysis was focused on the low deformation range, and especially on the yield region. Depending on the test temperature and blend composition, three types of response were identified, depending on whether plastic deformation is influenced: 1) by the PMMA secondary relaxation motions, 2) by the PVDF/PMMA glass transition motions, or 3) by the crystallite-constrained PVDF chains. |
Author | Jarray, Jlidi Vanhulle, Faustine Dubault, André Larbi, Fadhel Ben Cheikh Halary, Jean Louis |
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Snippet | Various PVDF/PMMA (poly(vinylidene fluoride)/poly(methyl methacrylate)) blends were selected for mechanical testing in compression. At low PVDF content (less... Abstract Various PVDF/PMMA (poly(vinylidene fluoride)/poly(methyl methacrylate)) blends were selected for mechanical testing in compression. At low PVDF... |
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SubjectTerms | Blends Degree of crystallinity Fluorides Glass transition mechanical relaxation Plastic deformation poly(methyl methacrylate) poly(vinylidene fluoride) Polymer blends Polymethyl methacrylates Polyvinylidene fluorides |
Title | Thermal and mechanical behavior of amorphous and semi-crystalline poly(vinylidene fluoride)/poly(methyl methacrylate) blends |
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