Asymmetric hydrosilylation of alkenes with alkoxyhydrosilanes catalyzed by chiral bis(oxazolinyl)phenyl-rhodium complex

Asymmetric addition of alkoxyhydrosilanes to styrene derivatives was examined with chiral bis(oxazolinyl)phenyl-rhodium complex to give moderate ratios (up to 77:23) of alpha- and beta-adducts and high enantioselectivity (up to 95% for the alpha-adduct).

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Published inSynlett no. 12; pp. 2099 - 2102
Main Authors Tsuchiya, Y, Uchimura, H, Kobayashi, K, Nishiyama, H
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.10.2004
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ORGANIC-SYNTHESIS
AQUA COMPLEXES
INTRAMOLECULAR HYDROSILATION
STEREOCHEMISTRY
asymmetric catalysis
ALDOL-TYPE CONDENSATION
ALCOHOLS
CARBON BOND
bisoxazoline
hydrosilylation
SILAFUNCTIONAL COMPOUNDS
ENANTIOSELECTIVE ALLYLATION
rhodium
styrene
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Abstract Asymmetric addition of alkoxyhydrosilanes to styrene derivatives was examined with chiral bis(oxazolinyl)phenyl-rhodium complex to give moderate ratios (up to 77:23) of alpha- and beta-adducts and high enantioselectivity (up to 95% for the alpha-adduct).
AbstractList Asymmetric addition of alkoxyhydrosilanes to styrene derivatives was examined with chiral bis(oxazolinyl)phenyl-rhodium complex to give moderate ratios (up to 77:23) of alpha- and beta-adducts and high enantioselectivity (up to 95% for the alpha-adduct).
Author Tsuchiya, Y
Kobayashi, K
Uchimura, H
Nishiyama, H
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10.1021/ja017138h
10.1021/om020274q
10.1021/om0305162
10.1021/om011011j
10.1021/jo001614p
10.1021/ja025617q
10.1021/om010018y
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Issue 12
Keywords ORGANIC-SYNTHESIS
AQUA COMPLEXES
INTRAMOLECULAR HYDROSILATION
STEREOCHEMISTRY
asymmetric catalysis
ALDOL-TYPE CONDENSATION
ALCOHOLS
CARBON BOND
bisoxazoline
hydrosilylation
SILAFUNCTIONAL COMPOUNDS
ENANTIOSELECTIVE ALLYLATION
rhodium
styrene
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PublicationTitle Synlett
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PublicationYear 2004
Publisher Thieme Medical Publishers
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Snippet Asymmetric addition of alkoxyhydrosilanes to styrene derivatives was examined with chiral bis(oxazolinyl)phenyl-rhodium complex to give moderate ratios (up to...
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Chemistry, Organic
Physical Sciences
Science & Technology
Title Asymmetric hydrosilylation of alkenes with alkoxyhydrosilanes catalyzed by chiral bis(oxazolinyl)phenyl-rhodium complex
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