The viscosity of five liquid hydrocarbons at pressures up to 250 MPa
This paper reports new measurements of the viscosity of toluene, n-pentane, n-hexane, n-octane, and n-decane at pressures up to 250 MPa in the temperature range 303 to 348 K. The measurements were performed with a vibrating-wire viscometer and with a relative method of evaluation. Calibration of the...
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Published in | International journal of thermophysics Vol. 13; no. 5; pp. 773 - 790 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
New York, NY
Springer
01.09.1992
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Abstract | This paper reports new measurements of the viscosity of toluene, n-pentane, n-hexane, n-octane, and n-decane at pressures up to 250 MPa in the temperature range 303 to 348 K. The measurements were performed with a vibrating-wire viscometer and with a relative method of evaluation. Calibration of the instrument was carried out with respect to reference values of the viscosity of the same liquids at their saturation vapour pressure. The viscosity measurements have a precision of [+-] 0.1% but the accuracy is limited by that of the calibration data to be [+-] 0.5%. The experimental data have been represented by polynomial functions of pressure for the purposes of interpolation. The data are also used as the most precise test yet applied to a representation of the viscosity of liquids based upon hard-sphere theory. 23 refs., 6 figs., 7 tabs. |
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AbstractList | This paper reports new measurements of the viscosity of toluene, n-pentane, n-hexane, n-octane, and n-decane at pressures up to 250 MPa in the temperature range 303 to 348 K. The measurements were performed with a vibrating-wire viscometer and with a relative method of evaluation. Calibration of the instrument was carried out with respect to reference values of the viscosity of the same liquids at their saturation vapour pressure. The viscosity measurements have a precision of [+-] 0.1% but the accuracy is limited by that of the calibration data to be [+-] 0.5%. The experimental data have been represented by polynomial functions of pressure for the purposes of interpolation. The data are also used as the most precise test yet applied to a representation of the viscosity of liquids based upon hard-sphere theory. 23 refs., 6 figs., 7 tabs. |
Author | WAKEHAM, W. A OLIVEIRA, C. M. B. P |
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Keywords | Octane Viscosity Liquid state Temperature Hydrocarbon Toluene Hard sphere model Experimental study Density Pentane Pressure Polynomial function Decane Interpolation Hexane Frequency Measurement method Organic compounds |
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References | CR2 B. Knapstad (CR5) 1989; 34 J. D. Isdale (CR17) 1979; 11 F. A. GonÇalves (CR4) 1987; 8 CR19 J. H. Dymond (CR8) 1980; 1 J. H. Dymond (CR18) 1989; 10 M. J. Assael (CR20) 1990; 11 M. J. Assael (CR3) 1992; 13 H. Kashiwagi (CR12) 1982; 3 T. Retsina (CR1) 1986; 43 J. H. Dymond (CR21) 1977 CR11 C. M. B. P. Oliveira (CR23) 1991 M. J. Assael (CR13) 1991; 3 H. Kashiwagi (CR6) 1982; 3 K. M. Reuck de (CR10) 1979; 19 M. J. Assael (CR22) 1992; 13 A. J. Easteal (CR7) 1987; 8 A. F. Collings (CR15) 1971; 67 J. H. Dymond (CR9) 1982; 14 D. W. Brazier (CR16) 1969; 47 J. H. Dymond (CR14) 1981; 2 |
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SubjectTerms | 400201 -- Chemical & Physicochemical Properties ALKANES ALKYLATED AROMATICS AROMATICS CALIBRATION Condensed matter: structure, mechanical and thermal properties DATA DATA COVARIANCES DECANE Diffusive momentum transport (including viscosity of liquids) Exact sciences and technology EXPERIMENTAL DATA HEXANE HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTERPOLATION MATERIALS SCIENCE MEASURING INSTRUMENTS NUMERICAL DATA NUMERICAL SOLUTION OCTANE ORGANIC COMPOUNDS PENTANE Physics PRESSURE DEPENDENCE SATURATION TEMPERATURE RANGE 0273-0400 K TEMPERATURE RANGE 360606 -- Other Materials-- Physical Properties-- (1992-) TOLUENE Transport properties of condensed matter (nonelectronic) VERY HIGH PRESSURE VISCOSIMETERS VISCOSITY |
Title | The viscosity of five liquid hydrocarbons at pressures up to 250 MPa |
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