Preparation of silver-coated glass frit and its application in silicon solar cells
A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating process. Infrared（IR） spectroscopy,field emission scanning electron microscopy（FESEM）, an...
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| Published in | Chinese physics B Vol. 25; no. 7; pp. 520 - 524 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
IOP Publishing
01.07.2016
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| Abstract | A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating process. Infrared（IR） spectroscopy,field emission scanning electron microscopy（FESEM）, and x-ray diffraction（XRD） were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions. |
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| AbstractList | A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating process. Infrared（IR） spectroscopy,field emission scanning electron microscopy（FESEM）, and x-ray diffraction（XRD） were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions. A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone (PVP) before the electroless plating process. Infrared (IR) spectroscopy, field emission scanning electron microscopy (FESEM), and x-ray diffraction (XRD) were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions. |
| Author | 向锋 李碧渊 黎应芬 周健 甘卫平 |
| AuthorAffiliation | School of Material Science and Engineering, Central South University, Changsha 410083, China |
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| Cites_doi | 10.1088/0957-4484/20/29/295604 10.1016/j.apsusc.2015.03.021 10.1016/j.matlet.2005.05.085 10.1016/j.jpcs.2013.09.006 10.1002/sia.v45.3 10.1002/aenm.201301465 10.1007/s11664-006-0218-6 10.1002/(ISSN)1097-4628 10.3969/j.issn.1001-8395.2014.06.028 10.1007/s00339-014-8890-5 10.1016/j.solmat.2008.10.021 10.1007/s00253-012-4603-1 10.1038/asiamat.2010.82 10.1007/s11051-013-1588-3 10.1109/PVSC.2005.1488377 10.1016/j.jallcom.2012.09.080 10.1007/s00339-013-7813-1 10.1016/j.matchemphys.2005.05.005 10.1016/j.ceramint.2013.06.014 10.1002/pip.v22.1 10.1109/WCPEC.2006.279710 10.1016/j.surfcoat.2013.06.115 10.1007/s11051-012-0975-5 10.1007/s11664-014-3012-x 10.1038/nnano.2011.145 10.1007/s10854-014-2216-4 10.1016/j.solmat.2006.03.040 |
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| Notes | A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating process. Infrared（IR） spectroscopy,field emission scanning electron microscopy（FESEM）, and x-ray diffraction（XRD） were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions. 11-5639/O4 electroless plating silver nanoparticle glass frit solar cell |
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| References | 22 23 24 25 26 27 28 29 Boies A M (17) 2009; 20 30 10 12 14 15 16 18 19 Elhachmi G T (13) 2015; 24 1 Sehrish S (11) 2015; 24 2 3 4 6 7 Yang X L (5) 2012; 41 8 9 20 21 |
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| SubjectTerms | electroless plating glass frit silver nanoparticle solar cell 制备 化学镀工艺 场发射扫描电子显微镜 应用 玻璃粉 硅太阳能电池 聚乙烯吡咯烷酮 镀银 |
| Title | Preparation of silver-coated glass frit and its application in silicon solar cells |
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