Study on Electrochemical Copolymerization of Aniline and 3-Methylthiophene in HMIMBF4 Ionic Liquid and Its Properties
Electrochemical polymerization of aniline and 3-methylthiophene has been accomplished in 1-methylimidazium tetrafluoroborate （HMIMBF4） ionic liquid. Homopolymer and copolymers of aniline and 3-methylthiophene were obtained successfully. The copolymer was studied by cyclic voltammetry and electrochem...
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| Published in | Chinese journal of chemistry Vol. 25; no. 3; pp. 268 - 271 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
01.03.2007
WILEY‐VCH Verlag Wiley |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1001-604X 1614-7065 |
| DOI | 10.1002/cjoc.200790053 |
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| Abstract | Electrochemical polymerization of aniline and 3-methylthiophene has been accomplished in 1-methylimidazium tetrafluoroborate （HMIMBF4） ionic liquid. Homopolymer and copolymers of aniline and 3-methylthiophene were obtained successfully. The copolymer was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The formation of copolymer has been confirmed by FT-IR and UV spectra. The atomic force microscope （AFM） was used for microstructural analysis. Both the homopolymer and the copolymer had the catalytic activity for the hydroquinone. |
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| AbstractList | Electrochemical polymerization of aniline and 3‐methylthiophene has been accomplished in 1‐methylimidazium tetrafluoroborate (HMIMBF4) ionic liquid. Homopolymer and copolymers of aniline and 3‐methylthiophene were obtained successfully. The copolymer was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The formation of copolymer has been confirmed by FT‐IR and UV spectra. The atomic force microscope (AFM) was used for microstructural analysis. Both the homopolymer and the copolymer had the catalytic activity for the hydroquinone. Electrochemical polymerization of aniline and 3-methylthiophene has been accomplished in 1-methylimidazium tetrafluoroborate （HMIMBF4） ionic liquid. Homopolymer and copolymers of aniline and 3-methylthiophene were obtained successfully. The copolymer was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The formation of copolymer has been confirmed by FT-IR and UV spectra. The atomic force microscope （AFM） was used for microstructural analysis. Both the homopolymer and the copolymer had the catalytic activity for the hydroquinone. |
| Author | 张爱健 张贵荣 杨广达 敖凤国 陆嘉星 |
| AuthorAffiliation | Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Chemistry Deparement, East China Normal University, Shanghai 200062, China |
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| Cites_doi | 10.1039/b209248b 10.1021/ja025818u 10.1016/j.matchemphys.2004.08.006 10.1021/jp049027l 10.1016/j.electacta.2004.10.017 |
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| Keywords | OXIDATION copolymerization POLYPYRROLE PYRROLE FILM 3-methylthiophene ELECTROPOLYMERIZATION THIOPHENE ionic liquid POLYANILINE ELECTROCATALYSIS aniline hydroquinone |
| Language | English |
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| Notes | 31-1547/O6 TQ324.8 copolymerization, aniline, 3-methylthiophene, ionic liquid, hydroquinone ArticleID:CJOC200790053 istex:B8989EBD9449FEC5C9AFD6F450C01E4BEDA02D22 the National Natural Science Foundation of China - No. 20573037 ark:/67375/WNG-XX4CGD5T-M the Natural Science Foundation of Shanghai - No. 05JC14070 Tel.: 0086‐021‐62233491 |
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| Snippet | Electrochemical polymerization of aniline and 3-methylthiophene has been accomplished in 1-methylimidazium tetrafluoroborate （HMIMBF4） ionic liquid.... Electrochemical polymerization of aniline and 3‐methylthiophene has been accomplished in 1‐methylimidazium tetrafluoroborate (HMIMBF4) ionic liquid.... Electrochemical polymerization of aniline and 3-methylthiophene has been accomplished in 1-methylimidazium tetrafluoroborate (HMIMBF4) ionic liquid.... |
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| SubjectTerms | 3-methylthiophene 3-甲基噻吩 aniline Chemistry Chemistry, Multidisciplinary copolymerization HMIMBF4离子液体 hydroquinone ionic liquid Physical Sciences Science & Technology 导电性质 电化学共聚合 |
| Title | Study on Electrochemical Copolymerization of Aniline and 3-Methylthiophene in HMIMBF4 Ionic Liquid and Its Properties |
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