Nickel-Incorporated, Nitrogen-Doped Graphene Nanoribbons as Efficient Electrocatalysts for Oxygen Evolution Reaction
We report a scalable method for the preparation of nickel incorporated nitrogen-doped graphene nanoribbon (Ni/NGNRs) through a facile solvothermal process. Significantly, we show that the incorporation of nitrogen functionalities on graphene nanoribbon with tunable nickel content not only catalyzes...
Saved in:
| Published in | Journal of the Electrochemical Society Vol. 165; no. 3; pp. H141 - H146 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
The Electrochemical Society
01.01.2018
|
| Online Access | Get full text |
Cover
Loading…
| Abstract | We report a scalable method for the preparation of nickel incorporated nitrogen-doped graphene nanoribbon (Ni/NGNRs) through a facile solvothermal process. Significantly, we show that the incorporation of nitrogen functionalities on graphene nanoribbon with tunable nickel content not only catalyzes efficiently the water oxidation reaction but enables to tweak the catalytic reactivity. Thus, Ni/NGNRs composite with higher nickel content exhibits an overpotential of 380 mV with a Tafel slope of 60 mV dec−1 to sustain 10 mA cm−2 under alkaline conditions. Furthermore, only a negligible current density drop is witnessed during the chronoamperometric studies suggesting the robust nature of the electrocatalyst. XPS analysis of the composite before and after polarization studies confirms the formation of nickel oxide on the exposed nickel nanoparticles during the electrochemical reaction but without any major adverse effect on the performance. We attribute the formation of nickel oxide on the exposed nickel nanoparticles as the major reason for the observed enhancement of electrocatalytic performance. |
|---|---|
| AbstractList | We report a scalable method for the preparation of nickel incorporated nitrogen-doped graphene nanoribbon (Ni/NGNRs) through a facile solvothermal process. Significantly, we show that the incorporation of nitrogen functionalities on graphene nanoribbon with tunable nickel content not only catalyzes efficiently the water oxidation reaction but enables to tweak the catalytic reactivity. Thus, Ni/NGNRs composite with higher nickel content exhibits an overpotential of 380 mV with a Tafel slope of 60 mV dec−1 to sustain 10 mA cm−2 under alkaline conditions. Furthermore, only a negligible current density drop is witnessed during the chronoamperometric studies suggesting the robust nature of the electrocatalyst. XPS analysis of the composite before and after polarization studies confirms the formation of nickel oxide on the exposed nickel nanoparticles during the electrochemical reaction but without any major adverse effect on the performance. We attribute the formation of nickel oxide on the exposed nickel nanoparticles as the major reason for the observed enhancement of electrocatalytic performance. |
| Author | Sekar, Archana Alwarappan, Subbiah Vijayaraghavan, Saranyan Kumar T., Prem Joy, Jaison Pillai, Vijayamohanan K |
| Author_xml | – sequence: 1 givenname: Jaison surname: Joy fullname: Joy, Jaison organization: Academy of Scientific & Innovative Research , CSIR Campus, India – sequence: 2 givenname: Archana surname: Sekar fullname: Sekar, Archana organization: CSIR-Central Electrochemical Research Institute , India – sequence: 3 givenname: Saranyan surname: Vijayaraghavan fullname: Vijayaraghavan, Saranyan organization: Academy of Scientific & Innovative Research , CSIR Campus, India – sequence: 4 givenname: Prem surname: Kumar T. fullname: Kumar T., Prem organization: CSIR-Central Electrochemical Research Institute , India – sequence: 5 givenname: Vijayamohanan K surname: Pillai fullname: Pillai, Vijayamohanan K organization: Academy of Scientific & Innovative Research , CSIR Campus, India – sequence: 6 givenname: Subbiah surname: Alwarappan fullname: Alwarappan, Subbiah organization: Academy of Scientific & Innovative Research , CSIR Campus, India |
| BookMark | eNp1kEFLAzEQhYMo2FZv_oAcPXRrJptudo9Say2UFkTPSzY7q6lrsiSp2H_vlgqC6GnewPceM29ITq2zSMgVsAmAKG74hGUMcpZuMZyQARRimkgAOCUDxiBNRDaFczIMYduvkAs5IHFt9Bu2ydJq5zvnVcR6TNcmeveCNrlzHdZ04VX3ihbpWlnnTVU5G6gKdN40Rhu0kc5b1L1Fq6jafYiBNs7Tzee-z6DzD9fuonGWPqLSB3FBzhrVBrz8niPyfD9_mj0kq81iObtdJZpneUxQKC05QyYrFHkKaS1kk0EvZC2QaSa1UGmVgcCiYvk0E43IkfNMy0qpgqcjMj7mau9C8NiUnTfvyu9LYOWhsZKXP431OP-FaxPV4eDolWn_M10fTcZ15dbtvO0_-hv9AtVdf9Y |
| CitedBy_id | crossref_primary_10_1021_acsaem_3c01571 crossref_primary_10_1149_1945_7111_abf79d crossref_primary_10_1039_D3NJ03885H crossref_primary_10_1016_j_jcis_2024_04_084 crossref_primary_10_1016_j_ccr_2021_214335 crossref_primary_10_1149_1945_7111_ab6c54 crossref_primary_10_1016_j_apcatb_2020_119800 crossref_primary_10_1088_2053_1591_ab3bf4 crossref_primary_10_1021_acs_jpca_0c02449 crossref_primary_10_1149_1945_7111_ac22cc crossref_primary_10_1016_j_jiec_2023_09_024 crossref_primary_10_1016_j_jcis_2024_09_227 crossref_primary_10_1016_j_jcis_2023_09_185 crossref_primary_10_1016_j_jtice_2018_07_040 crossref_primary_10_1149_2_0171902jes crossref_primary_10_1021_acs_energyfuels_2c02013 crossref_primary_10_1149_2_0231910jss crossref_primary_10_1149_1945_7111_ab6978 crossref_primary_10_1016_j_jcis_2023_08_008 crossref_primary_10_1016_j_jcis_2023_12_048 crossref_primary_10_1016_j_jcis_2023_01_035 crossref_primary_10_3390_catal10101164 crossref_primary_10_3390_ma13010114 crossref_primary_10_1039_D2RA00968D crossref_primary_10_1016_j_jcis_2024_01_072 crossref_primary_10_1149_2_0481811jes crossref_primary_10_1016_j_ijbiomac_2020_08_143 crossref_primary_10_1016_j_jics_2022_100775 crossref_primary_10_1088_2053_1591_ab50a9 crossref_primary_10_1149_1945_7111_ab697b crossref_primary_10_1002_er_7989 crossref_primary_10_1016_j_jcis_2024_07_025 crossref_primary_10_1016_j_cej_2024_157628 crossref_primary_10_1021_acsanm_4c01502 crossref_primary_10_1016_j_ces_2022_118402 crossref_primary_10_1021_acsaem_9b00199 crossref_primary_10_1149_2_1071908jes |
| Cites_doi | 10.1021/jacs.5b04142 10.1039/c2jm35506j 10.1021/am405735c 10.1002/adma.201305608 10.1002/anie.201403946 10.1039/C5TA03869C 10.1021/acscatal.5b02633 10.1038/srep32082 10.1038/ncomms3701 10.1039/C6QM00151C 10.1021/acs.chemmater.5b03148 10.1007/s10008-012-1938-6 10.1002/anie.201508404 10.1039/C5TA08714G 10.1038/srep26146 10.1002/adma.201001068 10.1021/acscatal.5b02571 10.1002/aenm.201500658 10.1038/ncomms10141 10.1021/ja403476v 10.1039/c3ee42383b 10.1126/science.1137014 10.1038/nmat3313 10.1007/s12274-012-0237-y 10.1088/2043-6262/4/2/025009 10.1021/ja104766z 10.1021/ja307507a 10.1039/c0cp00993h 10.1021/cr1002326 10.1002/anie.201306166 |
| ContentType | Journal Article |
| Copyright | 2018 The Electrochemical Society |
| Copyright_xml | – notice: 2018 The Electrochemical Society |
| DBID | AAYXX CITATION |
| DOI | 10.1149/2.0601803jes |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry |
| DocumentTitleAlternate | Nickel-Incorporated, Nitrogen-Doped Graphene Nanoribbons as Efficient Electrocatalysts for Oxygen Evolution Reaction |
| EISSN | 1945-7111 |
| EndPage | H146 |
| ExternalDocumentID | 10_1149_2_0601803jes 0601803JES |
| GrantInformation_xml | – fundername: CSIR grantid: OLP0088 – fundername: UGC |
| GroupedDBID | -~X .-4 .DC 0R~ 29L 41~ 5GY 6TJ 9M8 AATNI ABDNZ ABEFU ABJNI ABTAH ACBEA ACHIP ACYGS ADNWM AENEX AI. AKPSB ALMA_UNASSIGNED_HOLDINGS AOAED CJUJL CS3 DU5 EBS EJD F20 F5P H13 H~9 IOP JGOPE KOT MV1 MVM N5L NFQFE NHB REC RHI RNS ROL RPA TAE TN5 UPT VH1 VOH VQP WH7 XJT XOL YQT YXB ZY4 ~02 AAYXX ADEQX CITATION IZVLO |
| ID | FETCH-LOGICAL-c268t-e4ac720e07be48313d47f613137d4e0c07c4a3b614e9b08564f48e226c7baa923 |
| IEDL.DBID | IOP |
| ISSN | 0013-4651 |
| IngestDate | Thu Apr 24 23:05:58 EDT 2025 Tue Jul 01 01:05:05 EDT 2025 Wed Aug 21 03:33:43 EDT 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 3 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c268t-e4ac720e07be48313d47f613137d4e0c07c4a3b614e9b08564f48e226c7baa923 |
| Notes | 0601803JES |
| PageCount | 6 |
| ParticipantIDs | crossref_primary_10_1149_2_0601803jes iop_journals_10_1149_2_0601803jes crossref_citationtrail_10_1149_2_0601803jes |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 20180100 2018-00-00 |
| PublicationDateYYYYMMDD | 2018-01-01 |
| PublicationDate_xml | – month: 01 year: 2018 text: 20180100 |
| PublicationDecade | 2010 |
| PublicationTitle | Journal of the Electrochemical Society |
| PublicationTitleAlternate | J. Electrochem. Soc |
| PublicationYear | 2018 |
| Publisher | The Electrochemical Society |
| Publisher_xml | – name: The Electrochemical Society |
| References | 2018082015003016000_165.3.H141.29 2018082015003016000_165.3.H141.28 2018082015003016000_165.3.H141.27 2018082015003016000_165.3.H141.25 2018082015003016000_165.3.H141.24 2018082015003016000_165.3.H141.23 2018082015003016000_165.3.H141.8 2018082015003016000_165.3.H141.7 2018082015003016000_165.3.H141.9 2018082015003016000_165.3.H141.4 2018082015003016000_165.3.H141.22 2018082015003016000_165.3.H141.3 2018082015003016000_165.3.H141.21 2018082015003016000_165.3.H141.6 2018082015003016000_165.3.H141.20 2018082015003016000_165.3.H141.5 2018082015003016000_165.3.H141.2 2018082015003016000_165.3.H141.1 2018082015003016000_165.3.H141.19 2018082015003016000_165.3.H141.18 2018082015003016000_165.3.H141.17 2018082015003016000_165.3.H141.16 2018082015003016000_165.3.H141.15 2018082015003016000_165.3.H141.14 Zhang (2018082015003016000_165.3.H141.26) 2015; 5 2018082015003016000_165.3.H141.13 2018082015003016000_165.3.H141.12 2018082015003016000_165.3.H141.11 2018082015003016000_165.3.H141.10 2018082015003016000_165.3.H141.31 2018082015003016000_165.3.H141.30 |
| References_xml | – ident: 2018082015003016000_165.3.H141.7 doi: 10.1021/jacs.5b04142 – ident: 2018082015003016000_165.3.H141.29 doi: 10.1039/c2jm35506j – ident: 2018082015003016000_165.3.H141.20 doi: 10.1021/am405735c – ident: 2018082015003016000_165.3.H141.17 doi: 10.1002/adma.201305608 – ident: 2018082015003016000_165.3.H141.12 doi: 10.1002/anie.201403946 – ident: 2018082015003016000_165.3.H141.24 doi: 10.1039/C5TA03869C – ident: 2018082015003016000_165.3.H141.31 doi: 10.1021/acscatal.5b02633 – ident: 2018082015003016000_165.3.H141.25 doi: 10.1038/srep32082 – ident: 2018082015003016000_165.3.H141.19 doi: 10.1038/ncomms3701 – ident: 2018082015003016000_165.3.H141.16 doi: 10.1039/C6QM00151C – ident: 2018082015003016000_165.3.H141.11 doi: 10.1021/acs.chemmater.5b03148 – ident: 2018082015003016000_165.3.H141.6 doi: 10.1007/s10008-012-1938-6 – ident: 2018082015003016000_165.3.H141.9 doi: 10.1002/anie.201508404 – ident: 2018082015003016000_165.3.H141.30 doi: 10.1039/C5TA08714G – ident: 2018082015003016000_165.3.H141.28 doi: 10.1038/srep26146 – ident: 2018082015003016000_165.3.H141.14 doi: 10.1002/adma.201001068 – ident: 2018082015003016000_165.3.H141.5 doi: 10.1021/acscatal.5b02571 – ident: 2018082015003016000_165.3.H141.18 doi: 10.1002/aenm.201500658 – ident: 2018082015003016000_165.3.H141.23 doi: 10.1038/ncomms10141 – ident: 2018082015003016000_165.3.H141.2 doi: 10.1021/ja403476v – ident: 2018082015003016000_165.3.H141.13 doi: 10.1039/c3ee42383b – ident: 2018082015003016000_165.3.H141.1 doi: 10.1126/science.1137014 – ident: 2018082015003016000_165.3.H141.21 doi: 10.1038/nmat3313 – ident: 2018082015003016000_165.3.H141.15 doi: 10.1007/s12274-012-0237-y – volume: 5 start-page: 94016 volume-title: RSC Adv year: 2015 ident: 2018082015003016000_165.3.H141.26 article-title: A Stable Ni/SBA-15 Catalyst Prepared by the Ammonia Evaporation Method for Dry Reforming of Methane – ident: 2018082015003016000_165.3.H141.27 doi: 10.1088/2043-6262/4/2/025009 – ident: 2018082015003016000_165.3.H141.8 doi: 10.1021/ja104766z – ident: 2018082015003016000_165.3.H141.4 doi: 10.1021/ja307507a – ident: 2018082015003016000_165.3.H141.10 doi: 10.1039/c0cp00993h – ident: 2018082015003016000_165.3.H141.3 doi: 10.1021/cr1002326 – ident: 2018082015003016000_165.3.H141.22 doi: 10.1002/anie.201306166 |
| SSID | ssj0011847 |
| Score | 2.4232776 |
| Snippet | We report a scalable method for the preparation of nickel incorporated nitrogen-doped graphene nanoribbon (Ni/NGNRs) through a facile solvothermal process.... |
| SourceID | crossref iop |
| SourceType | Enrichment Source Index Database Publisher |
| StartPage | H141 |
| Title | Nickel-Incorporated, Nitrogen-Doped Graphene Nanoribbons as Efficient Electrocatalysts for Oxygen Evolution Reaction |
| URI | https://iopscience.iop.org/article/10.1149/2.0601803jes |
| Volume | 165 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT8MwDI5gHIADb8R4KUhwgow-0qY9Ith4SDyEmLRblaSeNDat09oh4NfjNt0YCCTErQe3iWLX_uLEnwk5FJ5wAimBaTv2GPc0Z0pzyVwHtOdrBLRF1fvtnX_V5Dctr1WmLopamGRQuv4aPhqiYLOEJbFteOrUcg6RwHKfIZ0lc27g-3nrguv7h8nxAW5bxPiW-7c3vsSfWRxjKpw0lklrPBFzi6RbG2Wqpt-_cTT-Y6YrZKmEmPTMiK2SGeivkfnzcWe3NbI4RUK4TjI0hi702HXOaFmwGkN8Qu862TBB42IXyQBiepnzWqNbpOiNk2FHKTRWKlNaLxgoMHDRuumnU6SD3tIspYiG6f3rG36D1l9KA6ePYAopNkizUX86v2JlLwamHT_IGHCphWOBJRTwwLXdmIs2QgHbFTEHS1sCNewqDPYQKoRxPm_zABDbaaGkRBS5SSr9pA9bhAoBIYh2HNoAnHtSea6vPC5DrhAOWrpKjscainRJVJ73y-hFpog6jJzoc12r5GgiPTAEHb_IHaCaovIPTX-U2f6DzA5ZQMwUmCzMLqlkwxHsIS7J1H5hgx_yvOCJ |
| linkProvider | IOP Publishing |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnZ1RT9swEMdPBSQ2HsbWbYINNk9iT8xtmjhxoj2h0tJu0KJpSDwgRbZzlTpQUzVhAj79LnFaOgTStLc8XBLLd_H9k_h-B7AnfemGSiE3rcTnwjeCayMU91w0fmBI0JZV7yeDoHcmvp375zX4uqiFSafV0t-gQwsKtlNYgW2jptsoGCKh4_3CrDlNRiuw5nuBV4Dz-8PTxS8EenWR853uD876Kwet0H2WUkp3Ey7mg7E7SS4b17lumLsHnMb_HO1LeFFJTXZgTV9BDSd1eNaed3irw8YSjPA15BQUl3jF-wXZsqQbY_KFDcb5LKUg44fpFBN2VPCtaXlktCqns7HWFLRMZaxTkigogbGO7atTfha6zfKMkSpmw5tbugbr_K4Cnf1AW1DxBs66nZ_tHq96MnDjBmHOUSgjXQcdqVGEXstLhByRJGh5MhHoGEeSpz1NSR8jTXIuECMRImk8I7VSpCbfwuokneAWMCkxQjlKohaiEL7S5EXtCxUJTbLQMduwP_dSbCpgedE34yq2xdRR7Mb3c7sNnxfWUwvqeMLuE7kqrp7U7FGbd_9g8xHWTw-78XF_8P09PCcZFdoPMzuwms-ucZekSq4_lCH5B9-l5e0 |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Nickel-Incorporated%2C+Nitrogen-Doped+Graphene+Nanoribbons+as+Efficient+Electrocatalysts+for+Oxygen+Evolution+Reaction&rft.jtitle=Journal+of+the+Electrochemical+Society&rft.au=Joy%2C+Jaison&rft.au=Sekar%2C+Archana&rft.au=Vijayaraghavan%2C+Saranyan&rft.au=Kumar+T.%2C+Prem&rft.date=2018&rft.issn=0013-4651&rft.eissn=1945-7111&rft.volume=165&rft.issue=3&rft.spage=H141&rft.epage=H146&rft_id=info:doi/10.1149%2F2.0601803jes&rft.externalDBID=n%2Fa&rft.externalDocID=10_1149_2_0601803jes |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-4651&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-4651&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-4651&client=summon |