Luminescence and study of channels for cross-relaxation dependent on the concentration of Sm3+ under simultaneous UV-IR excitation in tellurite-germanate glasses
A spectroscopic evaluation of Sm3+ doped TeO2-GeO2-ZnO glasses (0.5, 1.0, 3.0 and 5.0%) was carried with aim to determinate the dominant process in the cross-relaxation mechanism at high and low concentrations of Sm3. A new experimental spectroscopic technique is proposed, based on the analysis of t...
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Published in | Journal of alloys and compounds Vol. 854; p. 157076 |
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Abstract | A spectroscopic evaluation of Sm3+ doped TeO2-GeO2-ZnO glasses (0.5, 1.0, 3.0 and 5.0%) was carried with aim to determinate the dominant process in the cross-relaxation mechanism at high and low concentrations of Sm3. A new experimental spectroscopic technique is proposed, based on the analysis of the time evolution of the 600 m emission, corresponding to the 4G5/2 → 6H7/2 transition, obtained under spatial and temporal simultaneous excitation at 355 nm and into the infrared (950, 1085 1236, 1380 nm). It was possible to determine that at low Sm3+ content the dominant channel for cross relaxation is 4G5/2 + 6H5/2 → 6F5/2 + 6F11/2 and at high concentrations are: 4G5/2 + 6H5/2 → 6F7/2 + 6F9/2, 4G5/2 + 6H5/2 → 6F9/2 + 6F7/2, 4G5/2 + 6H5/2 → 6F11/2 + 6F5/2, and the least contributor one being 4G5/2 + 6H5/2 → 6F5/2 + 6F11/2. It is reported the optical absorption and Raman spectroscopies, photoluminescence spectra and decay time profiles as a function of Sm3+ concentration. Emission spectra measurements indicated that concentration quenching is active in the samples, being 1.0 mol% the optimum concentration for luminescence of Sm3+ ions. The decay time of 4G5/2 level upon 403 nm excitation, at 0.5% of Sm3+, presents a decay curve single exponential, however, when the concentration increases, the time decay reduces and becomes non-exponential. The Inokuti-Hirayama model was used to infer that an electric dipole-dipole mechanism is the dominant interaction in the energy transfer process between Sm3+-Sm3+ ions.
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•Luminescence on TeO-GeO-ZnO glasses activated with Sm3+ under UV-IR simultaneous excitation.•Non-radiative resonant energy transfer between Sm3+ ions.•Determination of the dominant process in the cross-relaxation mechanism for cross-relaxation Sm3+. |
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AbstractList | A spectroscopic evaluation of Sm3+ doped TeO2-GeO2-ZnO glasses (0.5, 1.0, 3.0 and 5.0%) was carried with aim to determinate the dominant process in the cross-relaxation mechanism at high and low concentrations of Sm3. A new experimental spectroscopic technique is proposed, based on the analysis of the time evolution of the 600 m emission, corresponding to the 4G5/2 → 6H7/2 transition, obtained under spatial and temporal simultaneous excitation at 355 nm and into the infrared (950, 1085 1236, 1380 nm). It was possible to determine that at low Sm3+ content the dominant channel for cross relaxation is 4G5/2 + 6H5/2 → 6F5/2 + 6F11/2 and at high concentrations are: 4G5/2 + 6H5/2 → 6F7/2 + 6F9/2, 4G5/2 + 6H5/2 → 6F9/2 + 6F7/2, 4G5/2 + 6H5/2 → 6F11/2 + 6F5/2, and the least contributor one being 4G5/2 + 6H5/2 → 6F5/2 + 6F11/2. It is reported the optical absorption and Raman spectroscopies, photoluminescence spectra and decay time profiles as a function of Sm3+ concentration. Emission spectra measurements indicated that concentration quenching is active in the samples, being 1.0 mol% the optimum concentration for luminescence of Sm3+ ions. The decay time of 4G5/2 level upon 403 nm excitation, at 0.5% of Sm3+, presents a decay curve single exponential, however, when the concentration increases, the time decay reduces and becomes non-exponential. The Inokuti-Hirayama model was used to infer that an electric dipole-dipole mechanism is the dominant interaction in the energy transfer process between Sm3+-Sm3+ ions. A spectroscopic evaluation of Sm3+ doped TeO2-GeO2-ZnO glasses (0.5, 1.0, 3.0 and 5.0%) was carried with aim to determinate the dominant process in the cross-relaxation mechanism at high and low concentrations of Sm3. A new experimental spectroscopic technique is proposed, based on the analysis of the time evolution of the 600 m emission, corresponding to the 4G5/2 → 6H7/2 transition, obtained under spatial and temporal simultaneous excitation at 355 nm and into the infrared (950, 1085 1236, 1380 nm). It was possible to determine that at low Sm3+ content the dominant channel for cross relaxation is 4G5/2 + 6H5/2 → 6F5/2 + 6F11/2 and at high concentrations are: 4G5/2 + 6H5/2 → 6F7/2 + 6F9/2, 4G5/2 + 6H5/2 → 6F9/2 + 6F7/2, 4G5/2 + 6H5/2 → 6F11/2 + 6F5/2, and the least contributor one being 4G5/2 + 6H5/2 → 6F5/2 + 6F11/2. It is reported the optical absorption and Raman spectroscopies, photoluminescence spectra and decay time profiles as a function of Sm3+ concentration. Emission spectra measurements indicated that concentration quenching is active in the samples, being 1.0 mol% the optimum concentration for luminescence of Sm3+ ions. The decay time of 4G5/2 level upon 403 nm excitation, at 0.5% of Sm3+, presents a decay curve single exponential, however, when the concentration increases, the time decay reduces and becomes non-exponential. The Inokuti-Hirayama model was used to infer that an electric dipole-dipole mechanism is the dominant interaction in the energy transfer process between Sm3+-Sm3+ ions. [Display omitted] •Luminescence on TeO-GeO-ZnO glasses activated with Sm3+ under UV-IR simultaneous excitation.•Non-radiative resonant energy transfer between Sm3+ ions.•Determination of the dominant process in the cross-relaxation mechanism for cross-relaxation Sm3+. |
ArticleNumber | 157076 |
Author | Alvarez-Ramos, M.E. |
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Snippet | A spectroscopic evaluation of Sm3+ doped TeO2-GeO2-ZnO glasses (0.5, 1.0, 3.0 and 5.0%) was carried with aim to determinate the dominant process in the... |
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SubjectTerms | Cross relaxation Cross-relaxation Sm3 Decay Electric dipoles Emission analysis Emission spectra Energy transfer Excitation Germanium oxides Inokuti-Hirayama Low concentrations Luminescence Photoluminescence Samarium Tellurium dioxide TeO2-GeO2-ZnO UV-IR simultaneous excitation Zinc oxide |
Title | Luminescence and study of channels for cross-relaxation dependent on the concentration of Sm3+ under simultaneous UV-IR excitation in tellurite-germanate glasses |
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