Preparation and Characterization of Fe3O4/Ethiodized-oil Magnetic Fluids Used in Arterial Embolization Hyperthermia

Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy...

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Published inChinese journal of chemistry Vol. 30; no. 4; pp. 854 - 860
Main Author 罗志 王益明 洪若瑜 李洪钟
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Published Weinheim WILEY-VCH Verlag 01.04.2012
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Abstract Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy and vibrating sample magne- tometer. Then, the modified Fe3O4 NPs were dispersed in ethiodized-oil by mechanical agitation and ultrasonic vi- bration to obtain stable Fe3O4 /ethiodized-oil magnetic fluids (MFs). The magnetic properties and rheological prop- erties of the MFs were measured using a Gouy magnetic balance and a rotational rheometer, respectively. The satu- ration magnetization of the Fe3O4 modified by oleic acid was 52.1 Emu/g. Furthermore, the result showed that the inductive heating effect of oleic acid stabilized Fe3O4/ethiodized-oil MF was remarkable and it only took 650 s for the temperature rising from 25 ℃ to 65 ℃. The specific absorption rate of the MF was 50.16 W/(g of Fe). It had a potential application in arterial embolization hyperthermia.
AbstractList Fe3O4 nanoparticles (NPs) were prepared by the co‐precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X‐ray powder diffraction, transmission electron microscopy and vibrating sample magnetometer. Then, the modified Fe3O4 NPs were dispersed in ethiodized‐oil by mechanical agitation and ultrasonic vibration to obtain stable Fe3O4/ethiodized‐oil magnetic fluids (MFs). The magnetic properties and rheological properties of the MFs were measured using a Gouy magnetic balance and a rotational rheometer, respectively. The saturation magnetization of the Fe3O4 modified by oleic acid was 52.1 emu/g. Furthermore, the result showed that the inductive heating effect of oleic acid stabilized Fe3O4/ethiodized‐oil MF was remarkable and it only took 650 s for the temperature rising from 25°C to 65°C. The specific absorption rate of the MF was 50.16 W/(g of Fe). It had a potential application in arterial embolization hyperthermia. Fe3O4 nanoparticles (NPs) were prepared by the co‐precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X‐ray powder diffraction, transmission electron microscopy and vibrating sample magnetometer.
Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy and vibrating sample magne- tometer. Then, the modified Fe3O4 NPs were dispersed in ethiodized-oil by mechanical agitation and ultrasonic vi- bration to obtain stable Fe3O4 /ethiodized-oil magnetic fluids (MFs). The magnetic properties and rheological prop- erties of the MFs were measured using a Gouy magnetic balance and a rotational rheometer, respectively. The satu- ration magnetization of the Fe3O4 modified by oleic acid was 52.1 Emu/g. Furthermore, the result showed that the inductive heating effect of oleic acid stabilized Fe3O4/ethiodized-oil MF was remarkable and it only took 650 s for the temperature rising from 25 ℃ to 65 ℃. The specific absorption rate of the MF was 50.16 W/(g of Fe). It had a potential application in arterial embolization hyperthermia.
Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy and vibrating sample magnetometer. Then, the modified Fe3O4NPs were dispersed in ethiodized-oil by mechanical agitation and ultrasonic vibration to obtain stable Fe3O4/ethiodized-oil magnetic fluids (MFs). The magnetic properties and rheological properties of the MFs were measured using a Gouy magnetic balance and a rotational rheometer, respectively. The saturation magnetization of the Fe3O4 modified by oleic acid was 52.1 emu/g. Furthermore, the result showed that the inductive heating effect of oleic acid stabilized Fe3O4/ethiodized-oil MF was remarkable and it only took 650 s for the temperature rising from 25°C to 65°C. The specific absorption rate of the MF was 50.16 W/(g of Fe). It had a potential application in arterial embolization hyperthermia.
Author Luo, Zhi
Li, Hongzhong
Hong, Ruoyu
Wang, Yiming
AuthorAffiliation College of Chemistry, Chemical Engineering and Materials Science & Key Laboratory of Organic Synthesis of Jiangsu Province, Soochow University, SIP, Suzhou, Jiangsu 215123, China College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, China State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China
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ethiodized-oil, Fe3O4, magnetic properties, rehology, arterial embolization hyperthermia
Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The modified Fe3O4 NPs were characterized by Fourier transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy and vibrating sample magne- tometer. Then, the modified Fe3O4 NPs were dispersed in ethiodized-oil by mechanical agitation and ultrasonic vi- bration to obtain stable Fe3O4 /ethiodized-oil magnetic fluids (MFs). The magnetic properties and rheological prop- erties of the MFs were measured using a Gouy magnetic balance and a rotational rheometer, respectively. The satu- ration magnetization of the Fe3O4 modified by oleic acid was 52.1 Emu/g. Furthermore, the result showed that the inductive heating effect of oleic acid stabilized Fe3O4/ethiodized-oil MF was remarkable and it only took 650 s for the temperature rising from 25 ℃ to 65 ℃. The specific absorption rate of the MF was 50.16 W/(g of Fe). It had a potential application in arterial embolization hyperthermia.
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National Post-doctoral Science Fundation - No. 20090451176
the Commission of Science and Technology of Suzhou Municipality - No. YJS0917, SG0978
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the Key Lab. of Organic Synthesis of Jiangsu Province
Minjiang Scholarship of Fujian Province
Post-doctoral Science Fundation of Jiangsu Province
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the National Basic Research Program of China (973 Program) - No. 2009CB219904
Natural Science Fundation of Jiangsu Province - No. BK2011328
the National Natural Science Foundation of China (NSFC) - No. 20876100 and 20736004
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Snippet Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The...
Fe3O4 nanoparticles (NPs) were prepared by the co‐precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The...
Fe3O4 nanoparticles (NPs) were prepared by the co-precipitation of Fe3+ and Fe2+ with ammonium hydroxide, and were modified by four different surfactants. The...
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SubjectTerms Ammonium
arterial embolization hyperthermia
ethiodized-oil
Fe3O4
Fe3O4纳米粒子
Fourier transforms
Infrared spectroscopy
Iron oxides
Magnetic properties
rehology
傅立叶变换红外光谱仪
制备
动脉
栓塞
热疗
磁流体
表征
Title Preparation and Characterization of Fe3O4/Ethiodized-oil Magnetic Fluids Used in Arterial Embolization Hyperthermia
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