Lanthanide perfluoroalkylsulfonylamide catalysts for fluorous phase organic synthesis

Lanthanide perfluoroalkylsulfonylamide complexes catalyze the Friedel-Crafts acylation and Diels-Alder reaction more efficiently than AlCl3 and Yb(OTf)(3) in benzotrifluoride and hexafluoro-p-xylene.

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Bibliographic Details
Published inSynlett no. 12; pp. 1347 - 1348
Main Authors Nishikido, J, Nakajima, H, Saeki, T, Ishii, A, Mikami, K
Format Journal Article
LanguageEnglish
Published STUTTGART Thieme Medical Publishers 01.12.1998
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
LEWIS-ACID CATALYSTS
COMBINATORIAL SYNTHESIS
benzotrifluoride
lanthanide perfluoroalkylsulfonylamide complexes
Friedel-Crafts acylation
ALDOL REACTIONS
PONYTAILS
Diels-Alder reaction
hexafluoro-p-xylene
WATER
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Summary:Lanthanide perfluoroalkylsulfonylamide complexes catalyze the Friedel-Crafts acylation and Diels-Alder reaction more efficiently than AlCl3 and Yb(OTf)(3) in benzotrifluoride and hexafluoro-p-xylene.
ISSN:0936-5214
DOI:10.1055/s-1998-1990