Electrochemical Degradation of Tartrazine Dye in Aqueous Solution Using a Modified Gas Diffusion Electrode
The increasing use of synthetic dyes in commercial food processing has heightened the need for more effective methods of treating industrial wastewaters prior to discharge into the environment. The present report describes the efficient electrodegradation of tartrazine dye in dilute aqueous solution...
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| Published in | Journal of the Electrochemical Society Vol. 161; no. 9; pp. H438 - H442 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
The Electrochemical Society
01.01.2014
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| Online Access | Get full text |
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| Abstract | The increasing use of synthetic dyes in commercial food processing has heightened the need for more effective methods of treating industrial wastewaters prior to discharge into the environment. The present report describes the efficient electrodegradation of tartrazine dye in dilute aqueous solution using the electro-Fenton process with Fe (II) or Fe (III) as catalyst and a gas diffusion electrode modified with 5.0% cobalt phthalocyanine. The highest level of color removal (98.4% in 90 min) from solution and the most rapid decay in concentration (kapp 6.0 × 10−2 min−1) of tartrazine dye were achieved in the presence of 0.15 mmol Fe (II). Under these conditions, the amount of total organic carbon (TOC) removed in 90 min was maximal (75%) while energy consumed was minimal (219.0 kWh kg−1 TOC removed). The amount of residual iron was slightly higher than that allowed by the Brazilian authorities for dissolved Fe in wastewaters, indicating that further treatment of the effluent would be necessary. |
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| AbstractList | The increasing use of synthetic dyes in commercial food processing has heightened the need for more effective methods of treating industrial wastewaters prior to discharge into the environment. The present report describes the efficient electrodegradation of tartrazine dye in dilute aqueous solution using the electro-Fenton process with Fe (II) or Fe (III) as catalyst and a gas diffusion electrode modified with 5.0% cobalt phthalocyanine. The highest level of color removal (98.4% in 90 min) from solution and the most rapid decay in concentration (kapp 6.0 × 10−2 min−1) of tartrazine dye were achieved in the presence of 0.15 mmol Fe (II). Under these conditions, the amount of total organic carbon (TOC) removed in 90 min was maximal (75%) while energy consumed was minimal (219.0 kWh kg−1 TOC removed). The amount of residual iron was slightly higher than that allowed by the Brazilian authorities for dissolved Fe in wastewaters, indicating that further treatment of the effluent would be necessary. |
| Author | Barros, Willyam R. P. Alves, Suellen A. Franco, Poliana C. Steter, Juliana R. Lanza, Marcos R. V. Rocha, Robson S. |
| Author_xml | – sequence: 1 givenname: Willyam R. P. surname: Barros fullname: Barros, Willyam R. P. – sequence: 2 givenname: Suellen A. surname: Alves fullname: Alves, Suellen A. – sequence: 3 givenname: Poliana C. surname: Franco fullname: Franco, Poliana C. – sequence: 4 givenname: Juliana R. surname: Steter fullname: Steter, Juliana R. – sequence: 5 givenname: Robson S. surname: Rocha fullname: Rocha, Robson S. – sequence: 6 givenname: Marcos R. V. surname: Lanza fullname: Lanza, Marcos R. V. |
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| CitedBy_id | crossref_primary_10_1016_j_apsusc_2018_09_226 crossref_primary_10_1016_j_reactfunctpolym_2019_03_009 crossref_primary_10_1016_j_apsadv_2024_100577 crossref_primary_10_1016_j_apcatb_2019_01_071 crossref_primary_10_1007_s13762_024_05842_y crossref_primary_10_1016_j_scitotenv_2020_141541 crossref_primary_10_1149_2_0091414jes crossref_primary_10_1016_j_apcatb_2015_06_048 crossref_primary_10_1016_j_jece_2019_102930 crossref_primary_10_1016_j_susmat_2021_e00373 crossref_primary_10_1016_j_cej_2022_140697 crossref_primary_10_1016_j_jece_2019_103621 crossref_primary_10_1021_acsestengg_2c00228 crossref_primary_10_1016_j_jece_2017_08_041 |
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