Insights into complexation and enantioselectivity of uranyl‐2‐(2‐hydroxy‐3‐methoxyphenyl)‐9‐(2‐hydroxyphenyl)thiopyrano[3,2‐h]thiochromene‐4,7‐dione with R/S‐organophosphorus pesticides

• Published in: Applied organometallic chemistry Vol. 35; no. 9
• Main Authors: Yang, Rong, Xiao, Yang, Tao, Xue‐bing, Ma, Ming‐jie, Wu, Zhi‐lin, Liao, Li‐fu, Xiao, Xi‐lin, Nie, Chang‐ming
• Format: Journal Article
• Language: English
• Published: 01.09.2021
• Subjects: chiral organophosphorus pesticides; coordination; density functional theory (DFT); enantioselectivity recognition; Uranyl‐HTTDN

In order to explore the enantioselectivity of new uranyl receptors to chiral organophosphorus pesticides (COPs), we designed a novel ligand: 2‐(2‐hydroxy‐3‐methoxyphenyl)‐9‐(2‐hydroxyphenyl)thiopyrano[3,2‐h]thiochromene‐4,7‐dione (HTTDN) and constructed a new receptor of Uranyl‐HTTDN by complexation...