Ni(II) Salt-catalyzed Direct Aryl Thioetherification of 1-Naphthylamine and Its Derivative with Disulfides

• Published in: Chemistry letters Vol. 51; no. 6; pp. 669 - 672
• Main Authors: Jiang, Chunfeng, Liu, Kaixuan, Zhang, Le, Liu, Tian, Zhang, Nan, Xu, Youjun
• Format: Journal Article
• Language: English
• Published: OXFORD Oxford Univ Press 05.06.2022
• Subjects: Chemistry; Chemistry, Multidisciplinary; Physical Sciences; Science & Technology; FUNCTIONALIZATION; ALKYLATION; THIOLATION; C-H aryl thioetherification; DIRECT SULFENYLATION; 1,2,3,4-Tetrahydro-1-naphthylamine; Ni(II) salt catalytic system; C-H BONDS

The direct C-H aryl thioetherification of 1-naphthylamine and its derivative with diaryl disulfides was developed with a Ni(II) salt catalytic system under air. The protocol was compatible with a wide range of functional groups. 1-Naphthylamine and 1,2,3,4-tetrahydro-1-naphthylamine were converted i...