Post-synthetic cation exchange in the robust metal–organic framework MIL-101(Cr)

In this work an unambiguous proof of post-synthetic solvent-assisted cation exchange in the robust metal-organic framework MIL-101(Cr) is reported. Such substitution can alter directly the secondary building unit, which often defines the properties of the material.

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Bibliographic Details
Published inCrystEngComm Vol. 15; no. 47; pp. 10175 - 10178
Main Authors Szilágyi, Petra Á., Serra-Crespo, Pablo, Dugulan, Iulian, Gascon, Jorge, Geerlings, Hans, Dam, Bernard
Format Journal Article
LanguageEnglish
Published 01.01.2013
Subjects
Cation exchanging
Metal-organic frameworks
Proving
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Summary:In this work an unambiguous proof of post-synthetic solvent-assisted cation exchange in the robust metal-organic framework MIL-101(Cr) is reported. Such substitution can alter directly the secondary building unit, which often defines the properties of the material.
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ISSN:1466-8033
1466-8033
DOI:10.1039/c3ce42006j