A novel high-throughput Raman spectrometer for polarization difference measurements
A Raman backscattering instrument which, for the first time, takes full advantage of the enormous étendue of modern holographic transmission grating spectrographs in single sample measurements is described. Developed primarily as the basic design of a new generation of Raman optical activity spectro...
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Published in | Journal of Raman spectroscopy Vol. 30; no. 9; pp. 841 - 852 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Chichester, UK
John Wiley & Sons, Ltd
01.09.1999
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Abstract | A Raman backscattering instrument which, for the first time, takes full advantage of the enormous étendue of modern holographic transmission grating spectrographs in single sample measurements is described. Developed primarily as the basic design of a new generation of Raman optical activity spectrometers, it inherently has the capability also to measure precisely and rapidly the degree of circularity of scattered light, and thus reversal coefficients. Its novel dual‐channel design allows the simultaneous measurement of right and left circular scattered light and drastically reduces sensitivity to particulate matter and thermal Schlieren in the sample. As examples the rapid and precise measurement of the degree of circularity of optically inactive substances and of the vibrational Raman optical activity of D‐carnitine·HCl is presented. Copyright © 1999 John Wiley & Sons, Ltd. |
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AbstractList | A Raman backscattering instrument which, for the first time, takes full advantage of the enormous étendue of modern holographic transmission grating spectrographs in single sample measurements is described. Developed primarily as the basic design of a new generation of Raman optical activity spectrometers, it inherently has the capability also to measure precisely and rapidly the degree of circularity of scattered light, and thus reversal coefficients. Its novel dual‐channel design allows the simultaneous measurement of right and left circular scattered light and drastically reduces sensitivity to particulate matter and thermal Schlieren in the sample. As examples the rapid and precise measurement of the degree of circularity of optically inactive substances and of the vibrational Raman optical activity of D‐carnitine·HCl is presented. Copyright © 1999 John Wiley & Sons, Ltd. |
Author | Hug, Werner Hangartner, Gilbert |
Author_xml | – sequence: 1 givenname: Werner surname: Hug fullname: Hug, Werner email: werner.hug@unifr.ch organization: Institute of Physical Chemistry, University of Fribourg, Pérolles, CH-1700 Fribourg, Switzerland – sequence: 2 givenname: Gilbert surname: Hangartner fullname: Hangartner, Gilbert organization: Institute of Physical Chemistry, University of Fribourg, Pérolles, CH-1700 Fribourg, Switzerland |
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Cites_doi | 10.1364/OPN.9.9.000059 10.1002/jrs.1250250703 10.1016/0009-2614(88)85109-1 10.1002/jrs.1250130108 10.1016/0030-4018(81)90306-0 10.1039/fd9949900035 10.1080/00268977100101091 10.1080/00268979100100351 10.1021/ja00852a049 10.1021/ja00783a058 10.1016/0301-0104(85)87100-7 10.1016/0009-2614(91)87138-2 10.1016/0009-2614(89)87460-3 10.1366/0003702814731815 10.1002/jrs.1250010504 10.1002/andp.19314030707 10.1002/jrs.1250010604 10.1016/0009-2614(79)80012-3 10.1366/0003702934067216 10.1366/000370274774333028 10.1364/OPN.7.2.000034 10.1002/jrs.1250230706 10.1366/0003702904086335 10.1002/(SICI)1097-4555(199708)28:8<627::AID-JRS144>3.0.CO;2-R |
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Title | A novel high-throughput Raman spectrometer for polarization difference measurements |
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