Laser-induced Fluorescence and Dispersed Fluorescence Spectroscopy of NiB: Identification of a New 2Π State in 19000–22100 cm−1
The laser-induced fluorescence excitation spectra of jet-cooled NiB radicals have been recorded in the energy range of 19000–22100 cm−1. Eleven bands have been assigned to the [20.77]2Π-X 2Σ+ transition system for the first time. The dispersed fluorescence spectra related to most of these bands have...
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| Published in | Chinese journal of chemical physics Vol. 23; no. 6; pp. 626 - 629 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
IOP Publishing
01.12.2010
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| Subjects | |
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| Abstract | The laser-induced fluorescence excitation spectra of jet-cooled NiB radicals have been recorded in the energy range of 19000–22100 cm−1. Eleven bands have been assigned to the [20.77]2Π-X
2Σ+ transition system for the first time. The dispersed fluorescence spectra related to most of these bands have been investigated. Vibrationally excited levels of the ground electronic state, with v″ up to 6, have been observed. In addition, the lifetimes for almost all the observed bands have also been measured. |
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| AbstractList | The laser-induced fluorescence excitation spectra of jet-cooled NiB radicals have been recorded in the energy range of 19000–22100 cm−1. Eleven bands have been assigned to the [20.77]2Π-X2Σ+ transition system for the first time. The dispersed fluorescence spectra related to most of these bands have been investigated. Vibrationally excited levels of the ground electronic state, with v″ up to 6, have been observed. In addition, the lifetimes for almost all the observed bands have also been measured. The laser-induced fluorescence excitation spectra of jet-cooled NiB radicals have been recorded in the energy range of 19000–22100 cm−1. Eleven bands have been assigned to the [20.77]2Π-X 2Σ+ transition system for the first time. The dispersed fluorescence spectra related to most of these bands have been investigated. Vibrationally excited levels of the ground electronic state, with v″ up to 6, have been observed. In addition, the lifetimes for almost all the observed bands have also been measured. |
| Author | Chen, Yang Wang, Li Qin, Cheng-bing Zhen, Jun-feng Zhang, Qun |
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| Cites_doi | 10.1063/1.2207615 10.1016/j.theochem.2005.05.014 10.1063/1.2821104 10.1080/00268970701390172 10.1016/j.cplett.2008.07.062 10.1006/jmsp.2000.8141 10.1063/1.2901964 |
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| Keywords | Laser-induced fluorescence Dispersed fluorescence NiB Direct current discharge |
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| Title | Laser-induced Fluorescence and Dispersed Fluorescence Spectroscopy of NiB: Identification of a New 2Π State in 19000–22100 cm−1 |
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