Spirobifluorenyl Phosphonic‐Based Ionic HOFs: Regulation Proton Transport and Single Crystal Superprotonic Conductivity

• Published in: Chinese journal of chemistry Vol. 43; no. 17; pp. 2129 - 2136
• Main Authors: Cao, Xiao‐Jie, Cao, Li‐Hui, Chen, Xu‐Yong, Qi, Simeng, Zhou, Bin, Hou, Xiao‐Ying
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY‐VCH Verlag GmbH & Co. KGaA 01.09.2025; Wiley Subscription Services, Inc
• Subjects: Conductivity; Crystal growth; Crystal structure; Crystals; Density functional theory; Density functional theory calculations; Hydrogen; Hydrogen bonding; Hydrogen bonds; Ionic hydrogen‐bonded organic frameworks; Multidimensional hydrogen bonds; Proton conduction; Proton transport path; Protons; Single crystal anisotropy; Single crystals; Spirobifluorenyl phosphonic‐based; Structural analysis; Superprotonic conductivity

Comprehensive Summary The design of ionic hydrogen‐bonded organic frameworks (iHOFs) with single crystal superprotonic conductivity is of great significance for studying the mechanism of proton conduction materials at molecular level. To regulate the proton transport path, this study focused on usin...